High-Pressure Synthesis, Structure, and Photoluminescence of a New KSbO3‑Type Bismuth Germanate Bi3Ge3O10.5

A new Bi3Ge3O10.5 compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under high pressure, the Bi3Ge3O10.5 crystallizes in a KSbO3-ype crystal structure. The crystal structure has been refined by the Rietveld method from syn...

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Published inInorganic chemistry Vol. 52; no. 4; pp. 2138 - 2141
Main Authors Cheng, Jinguang, Rettie, Alexander J. E, Suchomel, Matthew R, Zhou, Haidong, Yan, Jiaqiang, Song, Jie, Marshall, Luke G, Larregola, Sebastian A, Zhou, Jianshi, Goodenough, John B
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 18.02.2013
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Abstract A new Bi3Ge3O10.5 compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under high pressure, the Bi3Ge3O10.5 crystallizes in a KSbO3-ype crystal structure. The crystal structure has been refined by the Rietveld method from synchrotron X-ray diffraction data. Moreover, we have also characterized the Bi3Ge3O10.5 by X-ray photoelectron spectroscopy, photoluminescence, and specific heat.
AbstractList A new Bi3Ge3O10.5 compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under high pressure, the Bi3Ge3O10.5 crystallizes in a KSbO3-ype crystal structure. The crystal structure has been refined by the Rietveld method from synchrotron X-ray diffraction data. Moreover, we have also characterized the Bi3Ge3O10.5 by X-ray photoelectron spectroscopy, photoluminescence, and specific heat.
A new Bi(3)Ge(3)O(10.5) compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under high pressure, the Bi(3)Ge(3)O(10.5) crystallizes in a KSbO(3)-ype crystal structure. The crystal structure has been refined by the Rietveld method from synchrotron X-ray diffraction data. Moreover, we have also characterized the Bi(3)Ge(3)O(10.5) by X-ray photoelectron spectroscopy, photoluminescence, and specific heat.
A new Bi(3)Ge(3)O(10.5) compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under high pressure, the Bi(3)Ge(3)O(10.5) crystallizes in a KSbO(3)-ype crystal structure. The crystal structure has been refined by the Rietveld method from synchrotron X-ray diffraction data. Moreover, we have also characterized the Bi(3)Ge(3)O(10.5) by X-ray photoelectron spectroscopy, photoluminescence, and specific heat.A new Bi(3)Ge(3)O(10.5) compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under high pressure, the Bi(3)Ge(3)O(10.5) crystallizes in a KSbO(3)-ype crystal structure. The crystal structure has been refined by the Rietveld method from synchrotron X-ray diffraction data. Moreover, we have also characterized the Bi(3)Ge(3)O(10.5) by X-ray photoelectron spectroscopy, photoluminescence, and specific heat.
Author Rettie, Alexander J. E
Cheng, Jinguang
Marshall, Luke G
Zhou, Jianshi
Song, Jie
Zhou, Haidong
Yan, Jiaqiang
Suchomel, Matthew R
Goodenough, John B
Larregola, Sebastian A
AuthorAffiliation University of Tennessee
Argonne National Laboratory
Oak Ridge National Laboratory
University of Texas at Austin
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  givenname: John B
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  fullname: Goodenough, John B
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Snippet A new Bi3Ge3O10.5 compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under high...
A new Bi(3)Ge(3)O(10.5) compound has been synthesized under high pressure, P = 7 GPa, and 700 °C. Instead of the pyrochlore that is normally stabilized under...
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Title High-Pressure Synthesis, Structure, and Photoluminescence of a New KSbO3‑Type Bismuth Germanate Bi3Ge3O10.5
URI http://dx.doi.org/10.1021/ic3024277
https://www.ncbi.nlm.nih.gov/pubmed/23350864
https://www.proquest.com/docview/1288991713
https://www.osti.gov/biblio/1068757
Volume 52
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