Symmetry-Mismatched SBU Transformation in MOFs: Postsynthetic Metal Exchange from Zn to Fe and Its Effects on Gas Adsorption and Dye Selectivity
This research explores the alteration of metal–organic frameworks (MOFs) using a method called postsynthetic metal exchange. We focus on the shift from a Zn-based MOF containing a [Zn4O(COO)6] secondary building unit (SBU) of octahedral site symmetry (ANT-1(Zn)) to a Fe-based one with a [Fe3 IIIO...
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Published in | ACS applied materials & interfaces Vol. 15; no. 41; pp. 48406 - 48415 |
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Main Authors | , , , , , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
18.10.2023
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Subjects | |
Online Access | Get full text |
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