Chiral Co3Y Propeller-Shaped Chemosensory Platforms Based on 19F‑NMR

Two propeller-shaped chiral CoIII 3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-M...

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Published inInorganic chemistry Vol. 62; no. 6; pp. 2680 - 2693
Main Authors Audsley, Gabrielle, Carpenter, Harry, Essien, Nsikak B., Lai-Morrice, James, Al-Hilaly, Youssra, Serpell, Louise C., Akien, Geoffrey R., Tizzard, Graham J., Coles, Simon J., Ulldemolins, Cristina Pubill, Kostakis, George E.
Format Journal Article
LanguageEnglish
Published American Chemical Society 13.02.2023
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Abstract Two propeller-shaped chiral CoIII 3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (1H, 13C, and 19F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.
AbstractList Two propeller-shaped chiral CoIII 3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (1H, 13C, and 19F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.
Two propeller-shaped chiral Co III 3 Y III complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR ( 1 H, 13 C, and 19 F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19 F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented. This work explores the sensing and discrimination abilities of propeller-shaped chiral Co III 3 Y III complexes built from fluorinated ligands, thus providing an innovative sensing method using a 19 F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.
Author Audsley, Gabrielle
Carpenter, Harry
Akien, Geoffrey R.
Essien, Nsikak B.
Al-Hilaly, Youssra
Tizzard, Graham J.
Lai-Morrice, James
Kostakis, George E.
Coles, Simon J.
Ulldemolins, Cristina Pubill
Serpell, Louise C.
AuthorAffiliation Department of Chemistry
Sussex Neuroscience, School of Life Sciences
Mustansiriyah University
Department of Chemistry, School of Life Sciences
UK National Crystallography Service, Chemistry
Chemistry Department, College of Science
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Snippet Two propeller-shaped chiral CoIII 3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD),...
Two propeller-shaped chiral Co III 3 Y III complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction...
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Title Chiral Co3Y Propeller-Shaped Chemosensory Platforms Based on 19F‑NMR
URI http://dx.doi.org/10.1021/acs.inorgchem.2c03737
https://search.proquest.com/docview/2771333753
https://pubmed.ncbi.nlm.nih.gov/PMC9930122
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