Superparamagnetic-to-Diamagnetic Transition in Hydroxo-Bridged Trinuclear Copper(II) Complex Nanorods

• Published in: Journal of physical chemistry. C Vol. 114; no. 27; pp. 11723 - 11729
• Main Authors: Giri, S, Saha, S. K
• Format: Journal Article
• Language: English
• Published: American Chemical Society 15.07.2010
• Subjects: C: Nanops and Nanostructures

Although magnetic interaction in trinuclear Cu(II) complex is a widely studied subject, the field remains totally unexplored in their nanophase. Here, single crystalline nanorods of hydroxo-bridged trinuclear Cu complex with partial cubane (Cu3O4) core ([Cu3(μ3-OH)(SE)3](ClO4)2·0.5H2O, SE being the...