Synthesis of Well-Ordered Mesoporous Aluminosilicates with High Aluminum Contents: The Challenge and the Promise

SBA-15 has recently emerged as a potential material for the catalytic conversion of large molecules. Usually, SBA-15 has a low content of aluminum due to the conventional acidic synthesis medium. Although a few approaches have been adopted to prepare Al–SBA-15 with a high alumina content, it is stil...

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Published inInorganic chemistry Vol. 61; no. 30; pp. 11820 - 11829
Main Authors Deng, Yixiong, Zhou, Jiayu, Li, Gen, Liu, Honghai, Gao, Xionghou, Yue, Yuanyuan, Li, Haiyan, Xie, Fangming, Liu, Hongtao
Format Journal Article
LanguageEnglish
Published American Chemical Society 01.08.2022
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Abstract SBA-15 has recently emerged as a potential material for the catalytic conversion of large molecules. Usually, SBA-15 has a low content of aluminum due to the conventional acidic synthesis medium. Although a few approaches have been adopted to prepare Al–SBA-15 with a high alumina content, it is still challenging to prepare well-ordered Al–SBA-15 with a high alumina content. Here, we demonstrate a facile synthesis process in neutral mediums for the grafting of Al into the framework of SBA-15. This approach relies mainly on the dissociation of Si–O–Si bonds and the polymerization of Si–O–Si/Al bonds promoted by sodium persulfate (SPS) in neutral mediums. In this way, well-ordered Al–SBA-15 with a high aluminum content and enhanced acidity was obtained. Results of X-ray fluorescence spectroscopy (XRF) showed an n(SiO2)/n(Al2O3) ratio of 13.7, much lower than that of the conventional sample (21.7) obtained in acidic medium. The characterization results indicated the presence of a well-ordered Al-containing mesophase with high hydrothermal stability. Notably, the Al content and the acidity of Al–SBA-15 can be tuned by changing the SPS amount.
AbstractList SBA-15 has recently emerged as a potential material for the catalytic conversion of large molecules. Usually, SBA-15 has a low content of aluminum due to the conventional acidic synthesis medium. Although a few approaches have been adopted to prepare Al–SBA-15 with a high alumina content, it is still challenging to prepare well-ordered Al–SBA-15 with a high alumina content. Here, we demonstrate a facile synthesis process in neutral mediums for the grafting of Al into the framework of SBA-15. This approach relies mainly on the dissociation of Si–O–Si bonds and the polymerization of Si–O–Si/Al bonds promoted by sodium persulfate (SPS) in neutral mediums. In this way, well-ordered Al–SBA-15 with a high aluminum content and enhanced acidity was obtained. Results of X-ray fluorescence spectroscopy (XRF) showed an n(SiO2)/n(Al2O3) ratio of 13.7, much lower than that of the conventional sample (21.7) obtained in acidic medium. The characterization results indicated the presence of a well-ordered Al-containing mesophase with high hydrothermal stability. Notably, the Al content and the acidity of Al–SBA-15 can be tuned by changing the SPS amount.
Author Xie, Fangming
Zhou, Jiayu
Deng, Yixiong
Liu, Honghai
Li, Haiyan
Gao, Xionghou
Yue, Yuanyuan
Liu, Hongtao
Li, Gen
AuthorAffiliation National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering
China Petroleum Technology and Development Corporation
State Key Laboratory of Chemical Resource Engineering
Petrochemical Research Institute
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Cites_doi 10.1126/science.aaf1559
10.1021/jacs.8b00093
10.1039/C4RA03752A
10.1021/acs.iecr.9b03879
10.1016/j.catcom.2004.05.011
10.1016/j.apcatb.2015.11.038
10.1021/cm0343857
10.1021/cm000748g
10.1021/acs.energyfuels.6b02095
10.1016/j.jddst.2019.02.008
10.1016/j.colsurfa.2018.08.078
10.1016/j.micromeso.2021.110999
10.1007/s10934-010-9416-y
10.1016/j.micromeso.2022.111823
10.1016/j.micromeso.2013.07.005
10.1016/j.micromeso.2010.12.020
10.1016/j.cattod.2013.11.056
10.1134/s0023158416050098
10.1016/j.micromeso.2011.11.018
10.1007/s10934-014-9783-x
10.1071/CH15747
10.1021/ie302604m
10.1021/cm0619151
10.1021/acs.iecr.7b02362
10.1016/j.micromeso.2011.11.019
10.1021/acs.iecr.1c01500
10.1002/chem.201604368
10.1016/j.fuproc.2008.03.004
10.1021/acs.langmuir.1c01151
10.1021/am404911x
10.1016/j.jssc.2019.121079
10.3390/catal6120183
10.1021/acsami.0c04998
10.1126/science.279.5350.548
10.1016/j.micromeso.2005.12.013
10.1021/acs.iecr.7b01142
10.1016/j.micromeso.2013.11.039
10.1016/j.micromeso.2019.109640
10.1016/j.micromeso.2013.07.015
10.1016/j.micromeso.2007.12.021
10.1021/ef200723m
10.1021/cm9900756
10.1021/acs.iecr.8b01821
10.1016/j.jssc.2020.121319
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References ref9/cit9
ref45/cit45
ref6/cit6
ref36/cit36
ref3/cit3
ref27/cit27
ref18/cit18
ref11/cit11
ref25/cit25
ref16/cit16
ref29/cit29
ref32/cit32
ref23/cit23
ref39/cit39
ref14/cit14
ref8/cit8
ref5/cit5
ref31/cit31
ref2/cit2
ref43/cit43
ref34/cit34
ref37/cit37
ref28/cit28
ref40/cit40
ref20/cit20
ref17/cit17
ref10/cit10
ref26/cit26
ref35/cit35
ref19/cit19
ref21/cit21
ref12/cit12
ref15/cit15
ref42/cit42
ref41/cit41
ref22/cit22
ref13/cit13
ref33/cit33
ref4/cit4
ref30/cit30
ref1/cit1
ref24/cit24
ref38/cit38
ref44/cit44
ref7/cit7
References_xml – ident: ref37/cit37
  doi: 10.1126/science.aaf1559
– ident: ref38/cit38
  doi: 10.1021/jacs.8b00093
– ident: ref14/cit14
  doi: 10.1039/C4RA03752A
– ident: ref35/cit35
  doi: 10.1021/acs.iecr.9b03879
– ident: ref5/cit5
  doi: 10.1016/j.catcom.2004.05.011
– ident: ref16/cit16
  doi: 10.1016/j.apcatb.2015.11.038
– ident: ref28/cit28
  doi: 10.1021/cm0343857
– ident: ref25/cit25
  doi: 10.1021/cm000748g
– ident: ref17/cit17
  doi: 10.1021/acs.energyfuels.6b02095
– ident: ref4/cit4
  doi: 10.1016/j.jddst.2019.02.008
– ident: ref32/cit32
  doi: 10.1016/j.colsurfa.2018.08.078
– ident: ref44/cit44
  doi: 10.1016/j.micromeso.2021.110999
– ident: ref42/cit42
  doi: 10.1007/s10934-010-9416-y
– ident: ref45/cit45
  doi: 10.1016/j.micromeso.2022.111823
– ident: ref26/cit26
  doi: 10.1016/j.catcom.2004.05.011
– ident: ref11/cit11
  doi: 10.1016/j.micromeso.2013.07.005
– ident: ref29/cit29
  doi: 10.1016/j.micromeso.2010.12.020
– ident: ref22/cit22
  doi: 10.1016/j.cattod.2013.11.056
– ident: ref10/cit10
  doi: 10.1134/s0023158416050098
– ident: ref7/cit7
  doi: 10.1016/j.micromeso.2011.11.018
– ident: ref40/cit40
  doi: 10.1007/s10934-014-9783-x
– ident: ref8/cit8
  doi: 10.1071/CH15747
– ident: ref13/cit13
  doi: 10.1021/ie302604m
– ident: ref15/cit15
  doi: 10.1021/cm0619151
– ident: ref36/cit36
  doi: 10.1021/acs.iecr.7b02362
– ident: ref18/cit18
  doi: 10.1016/j.micromeso.2011.11.019
– ident: ref34/cit34
  doi: 10.1021/acs.iecr.1c01500
– ident: ref41/cit41
  doi: 10.1002/chem.201604368
– ident: ref3/cit3
  doi: 10.1016/j.fuproc.2008.03.004
– ident: ref33/cit33
  doi: 10.1021/acs.langmuir.1c01151
– ident: ref27/cit27
  doi: 10.1021/am404911x
– ident: ref2/cit2
  doi: 10.1016/j.jssc.2019.121079
– ident: ref9/cit9
  doi: 10.3390/catal6120183
– ident: ref43/cit43
  doi: 10.1021/acsami.0c04998
– ident: ref6/cit6
  doi: 10.1126/science.279.5350.548
– ident: ref20/cit20
  doi: 10.1016/j.micromeso.2005.12.013
– ident: ref31/cit31
  doi: 10.1021/acs.iecr.7b01142
– ident: ref12/cit12
  doi: 10.1016/j.micromeso.2013.11.039
– ident: ref39/cit39
  doi: 10.1016/j.micromeso.2019.109640
– ident: ref21/cit21
  doi: 10.1016/j.micromeso.2013.07.015
– ident: ref19/cit19
  doi: 10.1016/j.micromeso.2007.12.021
– ident: ref1/cit1
  doi: 10.1021/ef200723m
– ident: ref24/cit24
  doi: 10.1021/cm9900756
– ident: ref30/cit30
  doi: 10.1021/acs.iecr.8b01821
– ident: ref23/cit23
  doi: 10.1016/j.jssc.2020.121319
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Title Synthesis of Well-Ordered Mesoporous Aluminosilicates with High Aluminum Contents: The Challenge and the Promise
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