Five Roads That Converge at the Cyclic Peroxy-Criegee Intermediates: BF3‑Catalyzed Synthesis of β‑Hydroperoxy-β-peroxylactones

We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals, with H2O2. Strikingly, independent of the choice of starting materi...

Full description

Saved in:
Bibliographic Details
Published inJournal of organic chemistry Vol. 83; no. 21; pp. 13427 - 13445
Main Authors Vil’, Vera A, Gomes, Gabriel dos Passos, Ekimova, Maria V, Lyssenko, Konstantin A, Syroeshkin, Mikhail A, Nikishin, Gennady I, Alabugin, Igor V, Terent’ev, Alexander O
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 02.11.2018
Amer Chemical Soc
Subjects
acetates
chemical structure
Chemistry
Chemistry, Organic
enols
hydrogen peroxide
organic chemistry
oxidation
Physical Sciences
potential energy
roads
Science & Technology
silyl enol ethers
thermodynamics
HIGHLY EFFICIENT CATALYST
ELECTROORGANIC CHEMISTRY
ORGANIC PEROXIDES
BAEYER-VILLIGER REACTION
SILYL ENOL ETHERS
BRIDGED 1,2,4,5-TETRAOXANES
HYDROGEN-PEROXIDE
MALONYL PEROXIDES
PERACID OXIDATION
BORON-TRIFLUORIDE PVPP-BF3
Online AccessGet full text

Cover

Abstract We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals, with H2O2. Strikingly, independent of the choice of starting material, these reactions converge at the same β-hydroperoxy-β-peroxylactone products, i.e., the peroxy analogues of the previously elusive cyclic Criegee intermediate of the Baeyer–Villiger reaction. Computed thermodynamic parameters for the formation of the β-hydroperoxy-β-peroxylactones from silyl enol ethers, enol acetates, and cyclic acetals confirm that the β-peroxylactones indeed correspond to a deep energy minimum that connects a variety of the interconverting oxygen-rich species at this combined potential energy surface. The target β-hydroperoxy-β-peroxylactones were synthesized from β-ketoesters, and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals were obtained in 30–96% yields. These reactions proceed under mild conditions and open synthetic access to a broad selection of β-hydroperoxy-β-peroxylactones that are formed selectively even in those cases when alternative oxidation pathways can be expected. These β-peroxylactones are stable and can be useful for further synthetic transformations.
AbstractList We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals, with H2O2. Strikingly, independent of the choice of starting material, these reactions converge at the same β-hydroperoxy-β-peroxylactone products, i.e., the peroxy analogues of the previously elusive cyclic Criegee intermediate of the Baeyer–Villiger reaction. Computed thermodynamic parameters for the formation of the β-hydroperoxy-β-peroxylactones from silyl enol ethers, enol acetates, and cyclic acetals confirm that the β-peroxylactones indeed correspond to a deep energy minimum that connects a variety of the interconverting oxygen-rich species at this combined potential energy surface. The target β-hydroperoxy-β-peroxylactones were synthesized from β-ketoesters, and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals were obtained in 30–96% yields. These reactions proceed under mild conditions and open synthetic access to a broad selection of β-hydroperoxy-β-peroxylactones that are formed selectively even in those cases when alternative oxidation pathways can be expected. These β-peroxylactones are stable and can be useful for further synthetic transformations.
We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals, with H2O2. Strikingly, independent of the choice of starting material, these reactions converge at the same β-hydroperoxy-β-peroxylactone products, i.e., the peroxy analogues of the previously elusive cyclic Criegee intermediate of the Baeyer-Villiger reaction. Computed thermodynamic parameters for the formation of the β-hydroperoxy-β-peroxylactones from silyl enol ethers, enol acetates, and cyclic acetals confirm that the β-peroxylactones indeed correspond to a deep energy minimum that connects a variety of the interconverting oxygen-rich species at this combined potential energy surface. The target β-hydroperoxy-β-peroxylactones were synthesized from β-ketoesters, and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals were obtained in 30-96% yields. These reactions proceed under mild conditions and open synthetic access to a broad selection of β-hydroperoxy-β-peroxylactones that are formed selectively even in those cases when alternative oxidation pathways can be expected. These β-peroxylactones are stable and can be useful for further synthetic transformations.We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals, with H2O2. Strikingly, independent of the choice of starting material, these reactions converge at the same β-hydroperoxy-β-peroxylactone products, i.e., the peroxy analogues of the previously elusive cyclic Criegee intermediate of the Baeyer-Villiger reaction. Computed thermodynamic parameters for the formation of the β-hydroperoxy-β-peroxylactones from silyl enol ethers, enol acetates, and cyclic acetals confirm that the β-peroxylactones indeed correspond to a deep energy minimum that connects a variety of the interconverting oxygen-rich species at this combined potential energy surface. The target β-hydroperoxy-β-peroxylactones were synthesized from β-ketoesters, and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals were obtained in 30-96% yields. These reactions proceed under mild conditions and open synthetic access to a broad selection of β-hydroperoxy-β-peroxylactones that are formed selectively even in those cases when alternative oxidation pathways can be expected. These β-peroxylactones are stable and can be useful for further synthetic transformations.
We have discovered synthetic access to beta-hydroperoxy-beta-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, beta-ketoesters and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals, with H2O2. Strikingly, independent of the choice of starting material, these reactions converge at the same beta-hydroperoxy-beta-peroxylactone products, i.e., the peroxy analogues of the previously elusive cyclic Criegee intermediate of the Baeyer-Villiger reaction. Computed thermodynamic parameters for the formation of the beta-hydroperoxy-beta-peroxylactones from silyl enol ethers, enol acetates, and cyclic acetals confirm that the beta-peroxylactones indeed correspond to a deep energy minimum that connects a variety of the interconverting oxygen-rich species at this combined potential energy surface. The target beta-hydroperoxy-beta-peroxylactones were synthesized from beta-ketoesters, and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals were obtained in 30-96% yields. These reactions proceed under mild conditions and open synthetic access to a broad selection of beta-hydroperoxy-beta-peroxylactones that are formed selectively even in those cases when alternative oxidation pathways can be expected. These beta-peroxylactones are stable and can be useful for further synthetic transformations.
We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF₃-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals, with H₂O₂. Strikingly, independent of the choice of starting material, these reactions converge at the same β-hydroperoxy-β-peroxylactone products, i.e., the peroxy analogues of the previously elusive cyclic Criegee intermediate of the Baeyer–Villiger reaction. Computed thermodynamic parameters for the formation of the β-hydroperoxy-β-peroxylactones from silyl enol ethers, enol acetates, and cyclic acetals confirm that the β-peroxylactones indeed correspond to a deep energy minimum that connects a variety of the interconverting oxygen-rich species at this combined potential energy surface. The target β-hydroperoxy-β-peroxylactones were synthesized from β-ketoesters, and their silyl enol ethers, alkyl enol ethers, enol acetates, and cyclic acetals were obtained in 30–96% yields. These reactions proceed under mild conditions and open synthetic access to a broad selection of β-hydroperoxy-β-peroxylactones that are formed selectively even in those cases when alternative oxidation pathways can be expected. These β-peroxylactones are stable and can be useful for further synthetic transformations.
Author Lyssenko, Konstantin A
Vil’, Vera A
Terent’ev, Alexander O
Ekimova, Maria V
Alabugin, Igor V
Gomes, Gabriel dos Passos
Syroeshkin, Mikhail A
Nikishin, Gennady I
AuthorAffiliation Department of Chemistry and Biochemistry
Russian Academy of Sciences
D. I. Mendeleev University of Chemical Technology of Russia
A. N. Nesmeyanov Institute of Organoelement Compounds
N. D. Zelinsky Institute of Organic Chemistry
AuthorAffiliation_xml – name: D. I. Mendeleev University of Chemical Technology of Russia
– name: A. N. Nesmeyanov Institute of Organoelement Compounds
– name: Russian Academy of Sciences
– name: N. D. Zelinsky Institute of Organic Chemistry
– name: Department of Chemistry and Biochemistry
Author_xml – sequence: 1
  givenname: Vera A
  surname: Vil’
  fullname: Vil’, Vera A
  organization: N. D. Zelinsky Institute of Organic Chemistry
– sequence: 2
  givenname: Gabriel dos Passos
  orcidid: 0000-0002-8235-5969
  surname: Gomes
  fullname: Gomes, Gabriel dos Passos
  organization: Department of Chemistry and Biochemistry
– sequence: 3
  givenname: Maria V
  surname: Ekimova
  fullname: Ekimova, Maria V
  organization: D. I. Mendeleev University of Chemical Technology of Russia
– sequence: 4
  givenname: Konstantin A
  surname: Lyssenko
  fullname: Lyssenko, Konstantin A
  organization: Russian Academy of Sciences
– sequence: 5
  givenname: Mikhail A
  surname: Syroeshkin
  fullname: Syroeshkin, Mikhail A
  organization: N. D. Zelinsky Institute of Organic Chemistry
– sequence: 6
  givenname: Gennady I
  surname: Nikishin
  fullname: Nikishin, Gennady I
  organization: N. D. Zelinsky Institute of Organic Chemistry
– sequence: 7
  givenname: Igor V
  orcidid: 0000-0001-9289-3819
  surname: Alabugin
  fullname: Alabugin, Igor V
  email: alabugin@chem.fsu.edu
  organization: Department of Chemistry and Biochemistry
– sequence: 8
  givenname: Alexander O
  orcidid: 0000-0001-8018-031X
  surname: Terent’ev
  fullname: Terent’ev, Alexander O
  email: alterex@yandex.ru
  organization: N. D. Zelinsky Institute of Organic Chemistry
BookMark eNqNUs1u1DAQtlAR3RbOXH1EQlnssZ043CBi20qVQFDOkePMtl5l7SX2toQTh74Ar9IH6UPwJLhKJY4wl_k0832j-TsiBz54JOQlZ0vOgL8xNi43wS51xwC4fkIWXAEryprJA7JgOVgIKMUhOYpxw7IppZ6RQ8GE4rXUC3K7ctdIPwfTR3pxZRJtgr_G8RJpxukKaTPZwVn6CcfwfSqa0eElIj3zCcct9s4kjG_p-5X4_fNXY5IZph_Y0y-Tz9roIg1ren-Xc6dTP4bdXOT-rpjRYGzK88Tn5OnaDBFfPPpj8nX14aI5Lc4_npw1784LA6pKhRBVL6HWvKqMtRx61SsDUJXcSNFVutI9dsA7Uwm9lh1q6ECakunSlmjBiGPyaq67G8O3PcbUbl20OAzGY9jHFgCYrjlI-DeVg8qtlExlqp6pN9iFdbQOvcV2N7qtGac271zKWkoBD0g1Lpnkgm_C3qcsff3_0r_sfPV2E_ajz8tqOWsfXqGdg7Z9fAXxBw4Fqfw
Cites_doi 10.1021/ol800657m
10.1080/10426507.2011.610849
10.1021/acs.orglett.8b00645
10.1039/b300342f
10.1002/chem.201200815
10.1016/j.mencom.2015.11.019
10.1002/CHEM.200304931
10.1016/j.mencom.2014.11.010
10.1002/adsc.201600601
10.1021/jo100793j
10.1007/s11172-012-0239-7
10.1016/S1473-3099(15)00320-5
10.3390/molecules18056057
10.1021/jo991714z
10.1002/ejoc.201200795
10.1039/c4ob02372b
10.1016/j.tetlet.2008.11.055
10.1002/anie.201712651
10.1021/jacs.5b09888
10.1021/acs.joc.6b00041
10.1021/acs.orglett.7b00951
10.1126/science.1155165
10.1021/jo900226b
10.1021/acs.joc.8b00130
10.1021/ol060590r
10.1039/c4ob00276h
10.1039/c5sc02402a
10.1021/ol500835f
10.2298/JSC0911155O
10.1016/j.drudis.2009.05.008
10.1039/b707689d
10.1039/c2md00277a
10.1134/S1070363208040130
10.1086/591195
10.1016/j.tetlet.2010.05.072
10.1021/ol900262t
10.1016/j.tet.2018.01.045
10.1016/j.tetlet.2009.05.096
10.1055/s-0034-1378210
10.1021/jm9002523
10.1016/j.tetlet.2005.02.158
10.1021/ja908749u
10.1021/ol0521228
10.1021/cr030011l
10.1021/ol5020015
10.1002/anie.201610699
10.1002/ejoc.201601119
10.1021/jm800092x
10.1039/b711647k
10.1016/S0040-4039(03)01844-6
10.1039/c6ra28489b
10.1021/ol802709x
10.1021/jacs.7b05367
10.1039/c3ob27239g
10.1021/ol049171p
10.1002/anie.201712604
10.1021/jacs.5b07848
10.1021/ol2015434
10.1016/j.tetasy.2015.09.007
10.1002/chem.200800932
10.1139/V11-134
10.1055/s-0031-1289864
10.1002/ejoc.200500330
10.1021/ol900811m
10.1016/j.tet.2016.04.055
10.1016/j.tetlet.2017.08.064
10.3762/bjoc.12.162
10.1021/jo0708745
10.1021/jo101543q
10.3762/bjoc.10.6
ContentType Journal Article
DBID 17B
1KM
BLEPL
DTL
EGQ
HBEAY
7X8
7S9
L.6
DOI 10.1021/acs.joc.8b02218
DatabaseName Web of Knowledge
Index Chemicus
Web of Science Core Collection
Science Citation Index Expanded
Web of Science Primary (SCIE, SSCI & AHCI)
Web of Science - Science Citation Index Expanded - 2018
MEDLINE - Academic
AGRICOLA
AGRICOLA - Academic
DatabaseTitle Web of Science
MEDLINE - Academic
AGRICOLA
AGRICOLA - Academic
DatabaseTitleList
MEDLINE - Academic
Web of Science
AGRICOLA
Database_xml – sequence: 1
  dbid: 1KM
  name: Index Chemicus
  url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.IC
  sourceTypes:
    Enrichment Source
    Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1520-6904
EndPage 13445
ExternalDocumentID 000449443200045
b942462485
GrantInformation_xml – fundername: Russian Science Foundation; Russian Science Foundation (RSF)
  grantid: 18-13-00027
– fundername: National Science Foundation; National Science Foundation (NSF)
  grantid: CHE1800329
GroupedDBID -
.K2
29L
53G
55A
5RE
5VS
7~N
85S
AABXI
ABFLS
ABMVS
ABPPZ
ABPTK
ABUCX
ABUFD
ACGFS
ACJ
ACNCT
ACS
AEESW
AENEX
AFEFF
ALMA_UNASSIGNED_HOLDINGS
AQSVZ
BAANH
CJ0
CS3
D0L
DU5
DZ
EBS
ED
ED~
EJD
F20
F5P
GNL
IH9
IHE
JG
JG~
K2
LG6
P2P
PZZ
ROL
RXW
TAE
TN5
UI2
UKR
UPT
VF5
VG9
VQA
W1F
WH7
X
XFK
YZZ
---
-DZ
-~X
17B
1KM
4.4
AAHBH
ABBLG
ABJNI
ABLBI
ABQRX
ACBEA
ACGFO
ADHLV
AGXLV
AHGAQ
BLEPL
CUPRZ
DTL
GGK
GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED
GROUPED_WOS_WEB_OF_SCIENCE
IH2
TAF
XSW
YQT
ZCA
7X8
7S9
L.6
ID FETCH-LOGICAL-a257t-337d4298177acc12d5d5a22761a43b7878deb21ba738f4be82b24a6086c6ec2a3
IEDL.DBID ACS
ISICitedReferencesCount 24
ISICitedReferencesURI https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000449443200045
ISSN 0022-3263
1520-6904
IngestDate Thu Jul 10 20:42:00 EDT 2025
Fri Jul 11 09:27:11 EDT 2025
Fri Aug 29 16:14:13 EDT 2025
Wed Jul 09 13:51:22 EDT 2025
Thu Aug 27 13:42:52 EDT 2020
IsPeerReviewed true
IsScholarly true
Issue 21
Keywords HIGHLY EFFICIENT CATALYST
ELECTROORGANIC CHEMISTRY
ORGANIC PEROXIDES
BAEYER-VILLIGER REACTION
SILYL ENOL ETHERS
BRIDGED 1,2,4,5-TETRAOXANES
HYDROGEN-PEROXIDE
MALONYL PEROXIDES
PERACID OXIDATION
BORON-TRIFLUORIDE PVPP-BF3
Language English
LinkModel DirectLink
LogoURL https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg
MergedId FETCHMERGED-LOGICAL-a257t-337d4298177acc12d5d5a22761a43b7878deb21ba738f4be82b24a6086c6ec2a3
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ORCID 0000-0002-8235-5969
0000-0001-9289-3819
0000-0001-8018-031X
0000-0001-5754-922X
0000-0002-6847-6035
0000-0002-3500-1287
PMID 30351948
PQID 2125298605
PQPubID 23479
PageCount 19
ParticipantIDs acs_journals_10_1021_acs_joc_8b02218
proquest_miscellaneous_2220891242
webofscience_primary_000449443200045CitationCount
webofscience_primary_000449443200045
proquest_miscellaneous_2125298605
ProviderPackageCode JG~
55A
AABXI
GNL
VF5
7~N
ACJ
VG9
W1F
ACS
AEESW
AFEFF
.K2
ABMVS
ABUCX
IH9
BAANH
AQSVZ
ED~
UI2
PublicationCentury 2000
PublicationDate 2018-11-02
PublicationDateYYYYMMDD 2018-11-02
PublicationDate_xml – month: 11
  year: 2018
  text: 2018-11-02
  day: 02
PublicationDecade 2010
PublicationPlace WASHINGTON
PublicationPlace_xml – name: WASHINGTON
PublicationTitle Journal of organic chemistry
PublicationTitleAbbrev J ORG CHEM
PublicationTitleAlternate J. Org. Chem
PublicationYear 2018
Publisher American Chemical Society
Amer Chemical Soc
Publisher_xml – name: American Chemical Society
– name: Amer Chemical Soc
References DARMON, MJ (WOS:A1982PR58400011) 1982; 47
McCullough, KJ (WOS:000182984600016) 2003; 1
Sagot, E (WOS:000257721600006) 2008; 51
Gomes, GD (WOS:000399384700008) 2017; 56
PHILLIPSON, DW (WOS:A1983RX40100046) 1983; 105
Slack, RD (WOS:000301966800003) 2012; 3
MCCLURE, JD (WOS:A19626277B00074) 1962; 27
ANDRIAMIALISOA, RZ (WOS:A1985AMQ3400012) 1985; 26
Wang, Z (000449443200045.117) 2010
Sugimura, T (WOS:A1997XR68900031) 1997; 38
Yan, X (WOS:000297847700013) 2011
Alabugin, I. V (000449443200045.6) 2016
SAITO, I (WOS:A1983QM19200020) 1983; 24
Mori, N (WOS:000412613600022) 2017; 58
Klaper, M (WOS:000364355900006) 2015; 137
ADAM, W (WOS:A1981LG72200009) 1981; 22
RIECHE, A (WOS:A19628506A00031) 1962; 95
Tsedilin, AM (WOS:000367761800019) 2015; 25
Wang, C (WOS:000319446900077) 2013; 18
SNIDER, BB (WOS:A1992HF63900038) 1992; 114
Dembitsky, VM (WOS:000246484000002) 2007; 7
Kurouchi, H (WOS:000275084600060) 2010; 132
Rafiee, E (WOS:000299012500012) 2011; 89
Lee, SI (WOS:000350144600032) 2015; 13
LOWINGER, TB (WOS:A1995TD81600011) 1995; 36
Bunge, A (WOS:000267901800015) 2009; 50
Opsenica, DM (WOS:000272469700001) 2009; 74
Makhmudiyarova, NN (WOS:000376799800018) 2016; 72
CUBBON, RCP (WOS:A1968C293700005) 1968
ZHU, J (WOS:A1994PD85700022) 1994; 50
Paula, BRS (WOS:000390408200008) 2016; 358
Terent'ev, AO (WOS:000256176200013) 2008; 78
Van Arman, SA (WOS:000375890100007) 2016; 81
Gillard, RM (WOS:000430165700048) 2018; 57
Vil, VA (WOS:000427235600014) 2018; 57
JEFFORD, CW (WOS:A1990EL86300005) 1990; 20
Krow, G. R (000449443200045.58) 2004
GIBSON, DH (WOS:A1973P142900026) 1973
Sheng, XG (WOS:000402023500041) 2017; 19
Ghorai, P (WOS:000256762100019) 2008; 10
SHONO, T (WOS:A1975AT74200030) 1975; 97
ADAM, W (WOS:A1985AXS6600028) 1985; 24
Schwartz, C (000449443200045.91) 2009
Krasutsky, PA (WOS:000222706600013) 2004; 6
Halder, J (WOS:000363908100012) 2015; 26
Dussault, PH (WOS:000165752000001) 2000; 65
GONZALEZ, A (WOS:A1988R022600020) 1988; 44
Phyo, AP (WOS:000366664900034) 2016; 16
Keiser, J (WOS:000251390500008) 2007; 20
Singh, C (WOS:000228195200006) 2005; 46
Lee, S (WOS:000244695600005) 2007; 7
White, NJ (WOS:000255026100031) 2008; 320
Poldy, J (WOS:000309241600022) 2012; 2012
van Tonder, JH (WOS:000338110700033) 2014; 25
Terent'ev, AO (WOS:000265554900013) 2009; 74
Yamamoto, K (WOS:000184479300008) 2003; 9
Terent'ev, AO (WOS:000316803900010) 2013; 11
COCKER, W (WOS:A1975AM70100010) 1975
ADAM, W (WOS:A1990DB43100011) 1990; 31
Yaremenko, IA (WOS:000381258800001) 2016; 12
Shimkin, AA (WOS:000292212000019) 2011; 60
SHONO, T (WOS:A1974T067400028) 1974; 96
Zmitek, K (WOS:000237951800012) 2006; 8
Terent'ev, AO (WOS:000185605200029) 2003; 44
Adam, W. (000449443200045.5) 1988; 100
Juaristi, E (WOS:000407540200035) 2017; 139
Terent'ev, AO (WOS:000329820200001) 2014; 10
Dussault, P. H. (000449443200045.25) 2017
MARTIN, VA (WOS:A1990DY96200034) 1990; 112
Mokhtary, M (WOS:000323387900006) 2013; 32
Terent'ev, AO (WOS:000280398100019) 2010; 75
GARDNER, PD (WOS:A1956WB83700043) 1956; 78
Terent'ev, AO (WOS:000347139100010) 2014; 24
Yaremenko, IA (WOS:000430898500011) 2018; 83
Conga, RG (WOS:000279817400006) 2010; 51
Mayer, RJ (WOS:000432900200005) 2018; 20
BUTLER, AR (WOS:A1992HV37500001) 1992; 21
Bunge, A (WOS:000263383600006) 2009; 50
Einaga, H (WOS:000082423200019) 1999
Hoffman, RV (WOS:A1997WU86000032) 1997; 62
Mokhtary, M (WOS:000302363200003) 2012; 187
Zmitek, K (WOS:000251274700002) 2007; 5
RIECHE, A (WOS:A1969D931600011) 1969; 725
Chary, BC (WOS:000284080300052) 2010; 75
Terent'ev, AO (WOS:000233758600022) 2005; 54
HITCHCOCK, SR (WOS:A1990EH19300026) 1990
Griesbeck, AG (WOS:000236167900019) 2006; 3
Oh, DC (WOS:000262913500035) 2009; 11
Jefford, Charles W (MEDLINE:15600243) 2004; 5
Gandhi, H (WOS:000399242100013) 2017; 7
JEFFORD, CW (WOS:A1978FQ79300024) 1978
Nguyen, V. T. H. (000449443200045.78) 2006; 2006
ten Brink, GJ (WOS:000223812900011) 2004; 104
Erhardt, H (WOS:000390760000006) 2016; 2016
Brase, S (WOS:000232322700015) 2005; 2005
Tyumkina, TV (WOS:000430028400004) 2018; 74
Hao, HD (WOS:000293759100016) 2011; 13
MILAS, NA (WOS:A19633107B00029) 1963; 85
Wu, XF (WOS:000339470200002) 2014; 12
KADAS, I (WOS:A1995QE16600013) 1995; 126
Kumar, GS (WOS:000303497600001) 2012; 18
Efferth, T (WOS:000258570800011) 2008; 47
Li, Y (WOS:000266930900054) 2009; 11
ADAM, W (WOS:A1988R924700022) 1988; 27
Carbonnel, S (WOS:000082706200008) 1999; 319
Krow, G. R (000449443200045.59) 2001
Renz, M (WOS:000079499800001) 1999; 1999
Hamann, HJ (WOS:000258683600003) 2008; 14
BAUCH M (WOS:000449443200045.9) 2017; 30
HERNANDEZ, R (WOS:A1988R221700040) 1988; 29
Turmasova, AA (WOS:000321916700008) 2012; 61
BAILEY, WF (WOS:A1982NG33500068) 1982; 104
Gomes, GD (WOS:000365225300011) 2015; 6
Yerent'ev, AO (WOS:000223566500028) 2004; 53
Davis, JM (WOS:000233505700015) 2005; 7
Zmitek, K (WOS:000248793400026) 2007; 72
Borstnik, K (WOS:000179898500016) 2002; 32
Muraleedharan, KM (WOS:000269243000010) 2009; 14
Li, Y (WOS:000264622600054) 2009; 11
Kandur, WV (WOS:000336199200020) 2014; 16
Tang, YQ (WOS:000222199300002) 2004; 24
McCullough, KJ (WOS:000169171000002) 2001; 5
JUNG, MK (WOS:A1994NF09000015) 1994; 4
Griesbeck, AG (WOS:000266296200033) 2009; 52
Beddow, JE (WOS:000248731600024) 2007; 5
JOHNSON, WS (WOS:A1957WB80700064) 1957; 79
Hu, MY (WOS:000365148500037) 2015; 137
Hurlocker, B (WOS:000340517200057) 2014; 16
References_xml – volume: 10
  start-page: 2401
  year: 2008
  ident: WOS:000256762100019
  article-title: Synthesis of spiro-bisperoxyketals
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol800657m
– volume: 24
  start-page: 425
  year: 2004
  ident: WOS:000222199300002
  article-title: Synthetic peroxides as antimalarials
  publication-title: MEDICINAL RESEARCH REVIEWS
– volume: 44
  start-page: 6745
  year: 1988
  ident: WOS:A1988R022600020
  article-title: BIOMIMETIC SYNTHESIS OF 1,10-SEC-EUDESMANOLIDES
  publication-title: TETRAHEDRON
– volume: 187
  start-page: 321
  year: 2012
  ident: WOS:000302363200003
  article-title: POLYVINYLPOLYPYRROLIDONE-SUPPORTED BORON TRIFLUORIDE (PVPP-BF3): HIGHLY EFFICIENT CATALYST FOR CHEMOSELECTIVE OXYGENATION OF SULFIDES TO SULFONES BY H2O2
  publication-title: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  doi: 10.1080/10426507.2011.610849
– volume: 20
  start-page: 2816
  year: 2018
  ident: WOS:000432900200005
  article-title: Nucleophilic Reactivities of Bleach Reagents
  publication-title: ORGANIC LETTERS
  doi: 10.1021/acs.orglett.8b00645
– start-page: 2983
  year: 1968
  ident: WOS:A1968C293700005
  article-title: ORGANIC PEROXIDES CONTAINING FUNCTIONAL GROUPS 2. REACTION OF HYDROGEN PEROXIDE WITH BETA- AND GAMMA-OXO-ACIDS AND ESTERS
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC
– volume: 20
  start-page: 2589
  year: 1990
  ident: WOS:A1990EL86300005
  article-title: A NEW METHOD FOR THE SYNTHESIS OF GEM-DIHYDROPEROXIDES
  publication-title: SYNTHETIC COMMUNICATIONS
– volume: 2006
  start-page: 2865
  year: 2006
  ident: 000449443200045.78
  article-title: Synthesis of 4-Alkyl-and 4-(w-Chloroalkyl)-3-hydroxy-5-alkylidenebutenolides Based On Cyclizations of 4-Alkyl-and 4-(co-Chloroalkyl)-1,3-bis(trimethylsilyloxy)buta-1,3-dienes with Oxalyl Chloride
  publication-title: Synthesis
– volume: 1
  start-page: 1522
  year: 2003
  ident: WOS:000182984600016
  article-title: New approaches to the synthesis of spiro-peroxylactones
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/b300342f
– volume: 18
  start-page: 6124
  year: 2012
  ident: WOS:000303497600001
  article-title: Copper-Catalyzed Formation of C-O Bonds by Direct alpha-C-H Bond Activation of Ethers Using Stoichiometric Amounts of Peroxide in Batch and Continuous-Flow Formats
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.201200815
– volume: 25
  start-page: 454
  year: 2015
  ident: WOS:000367761800019
  article-title: How sensitive and accurate are routine NMR and MS measurements?
  publication-title: MENDELEEV COMMUNICATIONS
  doi: 10.1016/j.mencom.2015.11.019
– year: 2016
  ident: 000449443200045.6
  publication-title: Stereoelectronic Effects: A Bridge Between Structure and Reactivity
– volume: 4
  start-page: 931
  year: 1994
  ident: WOS:A1994NF09000015
  article-title: SYNTHESIS AND IN-VITRO ANTI-HUMAN-IMMUNODEFICIENCY-VIRUS ACTIVITY OF ARTEMISININ (QINGHAOSU)-RELATED TRIOXANES
  publication-title: BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
– volume: 53
  start-page: 681
  year: 2004
  ident: WOS:000223566500028
  article-title: Synthesis of peroxide compounds by the BF3-catalyzed reaction of acetals and enol ethers with H2O2
  publication-title: RUSSIAN CHEMICAL BULLETIN
– volume: 9
  start-page: 3242
  year: 2003
  ident: WOS:000184479300008
  article-title: On the total synthesis and determination of the absolute configuration of rishirilide B: Exploitation of subtle effects to control the sense of cycloaddition of o-quinodimethides
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/CHEM.200304931
– volume: 24
  start-page: 345
  year: 2014
  ident: WOS:000347139100010
  article-title: A convenient synthesis of cyclopropane malonyl peroxide
  publication-title: MENDELEEV COMMUNICATIONS
  doi: 10.1016/j.mencom.2014.11.010
– volume: 62
  start-page: 2458
  year: 1997
  ident: WOS:A1997WU86000032
  article-title: Synthesis and reactions of 3-(nosyloxy)-2-keto esters
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
– year: 2010
  ident: 000449443200045.117
  publication-title: Comprehensive Organic Name Reactions and Reagents
– volume: 358
  start-page: 3555
  year: 2016
  ident: WOS:000390408200008
  article-title: Bioreduction of alpha-Acetoxymethyl Enones: Proposal for an S(N)2 ' Mechanism Catalyzed by Enereductase
  publication-title: ADVANCED SYNTHESIS & CATALYSIS
  doi: 10.1002/adsc.201600601
– volume: 75
  start-page: 5065
  year: 2010
  ident: WOS:000280398100019
  article-title: Synthesis of Asymmetric Peroxides: Transition Metal (Cu, Fe, Mn, Co) Catalyzed Peroxidation of beta-Dicarbonyl Compounds with tert-Butyl Hydroperoxide
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo100793j
– volume: 29
  start-page: 5979
  year: 1988
  ident: WOS:A1988R221700040
  article-title: FRAGMENTATION OF ALKOXY RADICALS - MECHANISTIC ASPECTS OF THE TANDEM BETA-FRAGMENTATION-INTRAMOLECULAR FUNCTIONALIZATION REACTION
  publication-title: TETRAHEDRON LETTERS
– volume: 61
  start-page: 1733
  year: 2012
  ident: WOS:000321916700008
  article-title: Adamantylation of beta-dicarbonyl compounds
  publication-title: RUSSIAN CHEMICAL BULLETIN
  doi: 10.1007/s11172-012-0239-7
– year: 2004
  ident: 000449443200045.58
  publication-title: Organic Reactions
– volume: 16
  start-page: 61
  year: 2016
  ident: WOS:000366664900034
  article-title: Antimalarial activity of artefenomel (OZ439), a novel synthetic antimalarial endoperoxide, in patients with Plasmodium falciparum and Plasmodium vivax malaria: an open-label phase 2 trial
  publication-title: LANCET INFECTIOUS DISEASES
  doi: 10.1016/S1473-3099(15)00320-5
– volume: 18
  start-page: 6057
  year: 2013
  ident: WOS:000319446900077
  article-title: Substituted 3-Benzylcoumarins as Allosteric MEK1 Inhibitors: Design, Synthesis and Biological Evaluation as Antiviral Agents
  publication-title: MOLECULES
  doi: 10.3390/molecules18056057
– volume: 65
  start-page: 8407
  year: 2000
  ident: WOS:000165752000001
  article-title: Peroxycarbenium-mediated C-C bond formation: Applications to the synthesis of hydroperoxides and peroxides
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo991714z
– start-page: 1059
  year: 1990
  ident: WOS:A1990EH19300026
  article-title: EFFICIENT SYNTHESIS OF ALPHA-(HYDROXYMETHYL) KETONES NOT AVAILABLE THROUGH ALDOL-TYPE PROCESSES
  publication-title: SYNTHESIS-STUTTGART
– volume: 2012
  start-page: 5818
  year: 2012
  ident: WOS:000309241600022
  article-title: Identification of the First Alkenyl Chiloglottone Congener
  publication-title: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1002/ejoc.201200795
– start-page: 3585
  year: 1978
  ident: WOS:A1978FQ79300024
  article-title: OXYGENATION OF METHYL PARA-METHOXYPHENYLPYRUVATE - ALPHA-KETO-BETA-PEROXYLACTONE AND DIOXETANOL INTERMEDIATES
  publication-title: TETRAHEDRON LETTERS
– volume: 13
  start-page: 2745
  year: 2015
  ident: WOS:000350144600032
  article-title: Highly enantioselective catalytic 1,3-dipolar cycloadditions of alpha-alkyl diazoacetates: efficient synthesis of functionalized 2-pyrazolines
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/c4ob02372b
– volume: 50
  start-page: 524
  year: 2009
  ident: WOS:000263383600006
  article-title: A simple, efficient and versatile synthesis of primary gem-dihydroperoxides from aldehydes and hydrogen peroxide
  publication-title: TETRAHEDRON LETTERS
  doi: 10.1016/j.tetlet.2008.11.055
– volume: 57
  start-page: 3372
  year: 2018
  ident: WOS:000427235600014
  article-title: Interrupted Baeyer-Villiger Rearrangement: Building A Stereoelectronic Trap for the Criegee Intermediate
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201712651
– volume: 137
  start-page: 14496
  year: 2015
  ident: WOS:000365148500037
  article-title: gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/jacs.5b09888
– volume: 319
  start-page: 63
  year: 1999
  ident: WOS:000082706200008
  article-title: Introduction of a carboxyl group through an acetal as a new route to carboxylic acid derivatives of sugars
  publication-title: CARBOHYDRATE RESEARCH
– volume: 81
  start-page: 3528
  year: 2016
  ident: WOS:000375890100007
  article-title: A Hantzsch Amido Dihydropyridine as a Transfer Hydrogenation Reagent for alpha,beta-Unsaturated Ketones
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/acs.joc.6b00041
– volume: 38
  start-page: 6019
  year: 1997
  ident: WOS:A1997XR68900031
  article-title: Asymmetric Baeyer-Villiger reaction: Diastereodifferentiating peracid oxidation of chiral acetal in the presence of Lewis acid
  publication-title: TETRAHEDRON LETTERS
– volume: 19
  start-page: 2618
  year: 2017
  ident: WOS:000402023500041
  article-title: Tunable Aerobic Oxidative Hydroxylation/Dehydrogenative Homocoupling of Pyrazol-5-ones under Transition-Metal-Free Conditions
  publication-title: ORGANIC LETTERS
  doi: 10.1021/acs.orglett.7b00951
– volume: 36
  start-page: 8383
  year: 1995
  ident: WOS:A1995TD81600011
  article-title: THE TOTAL SYNTHESIS OF (+/-)K252A
  publication-title: TETRAHEDRON LETTERS
– volume: 320
  start-page: 330
  year: 2008
  ident: WOS:000255026100031
  article-title: Qinghaosu (Artemisinin): The price of success
  publication-title: SCIENCE
  doi: 10.1126/science.1155165
– volume: 74
  start-page: 3335
  year: 2009
  ident: WOS:000265554900013
  article-title: Facile and Selective Procedure for the Synthesis of Bridged 1,2,4,5-Tetraoxanes; Strong Acids As Cosolvents and Catalysts for Addition of Hydrogen Peroxide to beta-Diketones
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo900226b
– volume: 104
  start-page: 1769
  year: 1982
  ident: WOS:A1982NG33500068
  article-title: OXIDATION OF KETALS TO ORTHOCARBONATES - A DOUBLE BAEYER-VILLIGER REACTION
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 7
  start-page: 571
  year: 2007
  ident: WOS:000246484000002
  article-title: Natural peroxy anticancer agents
  publication-title: MINI-REVIEWS IN MEDICINAL CHEMISTRY
– volume: 97
  start-page: 6144
  year: 1975
  ident: WOS:A1975AT74200030
  article-title: ELECTROORGANIC CHEMISTRY .21. SELECTIVE FORMATION OF ALPHA-ACETOXY KETONES AND GENERAL SYNTHESIS OF 2,3-DISUBSTITUTED 2-CYCLOPENTENONES THROUGH ANODIC-OXIDATION OF ENOL ACETATES
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 83
  start-page: 4402
  year: 2018
  ident: WOS:000430898500011
  article-title: Ozone-Free Synthesis of Ozonides: Assembling Bicyclic Structures from 1,5-Diketones and Hydrogen Peroxide
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/acs.joc.8b00130
– volume: 21
  start-page: 85
  year: 1992
  ident: WOS:A1992HV37500001
  article-title: ARTEMISININ (QINGHAOSU) - A NEW TYPE OF ANTIMALARIAL DRUG
  publication-title: CHEMICAL SOCIETY REVIEWS
– volume: 8
  start-page: 2491
  year: 2006
  ident: WOS:000237951800012
  article-title: Iodine as a catalyst for efficient conversion of ketones to gem-dihydroperoxides by aqueous hydrogen peroxide
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol060590r
– volume: 24
  start-page: 1737
  year: 1983
  ident: WOS:A1983QM19200020
  article-title: SYNTHESIS OF ALPHA-SILYLOXYHYDROPEROXIDES FROM THE REACTION OF SILYL ENOL ETHERS AND HYDROGEN-PEROXIDE
  publication-title: TETRAHEDRON LETTERS
– volume: 12
  start-page: 5807
  year: 2014
  ident: WOS:000339470200002
  article-title: A powerful combination: recent achievements on using TBAI and TBHP as oxidation system
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/c4ob00276h
– volume: 6
  start-page: 6783
  year: 2015
  ident: WOS:000365225300011
  article-title: Stereoelectronic source of the anomalous stability of bis-peroxides
  publication-title: CHEMICAL SCIENCE
  doi: 10.1039/c5sc02402a
– volume: 96
  start-page: 3532
  year: 1974
  ident: WOS:A1974T067400028
  article-title: ELECTROORGANIC CHEMISTRY .12. ANODIC-OXIDATION OF ENOL ESTERS
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 5
  start-page: 866
  year: 2004
  ident: MEDLINE:15600243
  article-title: Synthetic peroxides as antimalarials.
  publication-title: Current opinion in investigational drugs (London, England : 2000)
– volume: 16
  start-page: 2650
  year: 2014
  ident: WOS:000336199200020
  article-title: Synthesis and Reactivity of 1,2-Dioxolanes from beta,gamma-Epoxy Ketones
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol500835f
– volume: 74
  start-page: 1155
  year: 2009
  ident: WOS:000272469700001
  article-title: Antimalarial peroxides
  publication-title: JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
  doi: 10.2298/JSC0911155O
– volume: 14
  start-page: 793
  year: 2009
  ident: WOS:000269243000010
  article-title: Progress in the development of peroxide-based anti-parasitic agents
  publication-title: DRUG DISCOVERY TODAY
  doi: 10.1016/j.drudis.2009.05.008
– volume: 24
  start-page: 1070
  year: 1985
  ident: WOS:A1985AXS6600028
  article-title: SYNTHESIS OF THE 1ST ALPHA-METHYLENE-BETA-PEROXYLACTONE - REGIOSPECIFIC ENE REACTION OF O-1(2) WITH ALPHA,BETA-UNSATURATED CARBOXYLIC-ACIDS
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
– volume: 78
  start-page: 3421
  year: 1956
  ident: WOS:A1956WB83700043
  article-title: ORGANIC PERACID OXIDATION OF SOME ENOL ESTERS INVOLVING REARRANGEMENT
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 5
  start-page: 601
  year: 2001
  ident: WOS:000169171000002
  article-title: Recent advances in the chemistry of cyclic peroxides
  publication-title: CURRENT ORGANIC CHEMISTRY
– volume: 5
  start-page: 2812
  year: 2007
  ident: WOS:000248731600024
  article-title: Asymmetric synthesis of beta(2)-amino acids: 2-substituted-3-aminopropanoic acids from N-acryloyl SuperQuat derivatives
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/b707689d
– start-page: 2507
  year: 1999
  ident: WOS:000082423200019
  article-title: Photooxygenation (O-1(2)) of silyl enol ethers derived from indan-1-ones: competitive formation of tricyclic 3-siloxy-1,2-dioxetane and alpha-silylperoxy ketone
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
– volume: 3
  start-page: 281
  year: 2012
  ident: WOS:000301966800003
  article-title: Antimalarial peroxides: advances in drug discovery and design
  publication-title: MEDCHEMCOMM
  doi: 10.1039/c2md00277a
– volume: 78
  start-page: 592
  year: 2008
  ident: WOS:000256176200013
  article-title: Oxidation of alkenes with hydrogen peroxide, catalyzed by boron trifluoride. Synthesis of vicinal methoxyalkanols
  publication-title: RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  doi: 10.1134/S1070363208040130
– volume: 47
  start-page: 804
  year: 2008
  ident: WOS:000258570800011
  article-title: The antiviral activities of artemisinin and artesunate
  publication-title: CLINICAL INFECTIOUS DISEASES
  doi: 10.1086/591195
– volume: 51
  start-page: 3890
  year: 2010
  ident: WOS:000279817400006
  article-title: A concise synthesis of the steroidal core of clathsterol
  publication-title: TETRAHEDRON LETTERS
  doi: 10.1016/j.tetlet.2010.05.072
– volume: 11
  start-page: 1615
  year: 2009
  ident: WOS:000264622600054
  article-title: A Broadly Applicable Mild Method for the Synthesis of gem-Diperoxides from Corresponding Ketones or 1,3-Dioxolanes
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol900262t
– volume: 26
  start-page: 3563
  year: 1985
  ident: WOS:A1985AMQ3400012
  article-title: ALPHA-HYDROXYLATION OF BETA-DICARBONYL COMPOUNDS
  publication-title: TETRAHEDRON LETTERS
– year: 2017
  ident: 000449443200045.25
  publication-title: Organic Peroxides. Safety Issues
– volume: 74
  start-page: 1749
  year: 2018
  ident: WOS:000430028400004
  article-title: Synthesis, molecular structure, conformation and biological activity of Ad-substituted &ITN&IT-aryl-tetraoxaspiroalkanes
  publication-title: TETRAHEDRON
  doi: 10.1016/j.tet.2018.01.045
– volume: 114
  start-page: 1790
  year: 1992
  ident: WOS:A1992HF63900038
  article-title: TOTAL SYNTHESIS OF (+/-)-CHONDRILLIN, (+/-)-PLAKORIN, AND RELATED PEROXY KETALS - DEVELOPMENT OF A GENERAL-ROUTE TO 3,6-DIHYDRO-1,2-DIOXIN-3-OLS
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 27
  start-page: 1536
  year: 1988
  ident: WOS:A1988R924700022
  article-title: ALPHA-METHYLENE-BETA-LACTONE, A NOVEL HETEROCYCLIC RING-SYSTEM VIA DEOXYGENATION OF ALPHA-METHYLENE-BETA-PEROXYLACTONES WITH TRIPHENYLPHOSPHANE
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
– volume: 50
  start-page: 4629
  year: 2009
  ident: WOS:000267901800015
  article-title: Enantioselective epoxidation of 2-substituted 1,4-naphthoquinones using gem-dihydroperoxides
  publication-title: TETRAHEDRON LETTERS
  doi: 10.1016/j.tetlet.2009.05.096
– year: 2001
  ident: 000449443200045.59
  publication-title: Encyclopedia of Reagents for Organic Synthesis
– volume: 25
  start-page: 1629
  year: 2014
  ident: WOS:000338110700033
  article-title: gem-Bishydroperoxides
  publication-title: SYNLETT
  doi: 10.1055/s-0034-1378210
– volume: 7
  start-page: 411
  year: 2007
  ident: WOS:000244695600005
  article-title: Artemisinin, promising lead natural product for various drug developments
  publication-title: MINI-REVIEWS IN MEDICINAL CHEMISTRY
– volume: 3
  start-page: 247
  year: 2006
  ident: WOS:000236167900019
  article-title: Synthetic approaches to polar antimalarial 1,2,4-trioxanes from C-5-aldehyde and ipsdienol
  publication-title: LETTERS IN ORGANIC CHEMISTRY
– volume: 52
  start-page: 3420
  year: 2009
  ident: WOS:000266296200033
  article-title: Antimalarial Peroxide Dyads from Natural Artemisinin and Hydroxyalkylated 1,2,4-Trioxanes
  publication-title: JOURNAL OF MEDICINAL CHEMISTRY
  doi: 10.1021/jm9002523
– volume: 46
  start-page: 2757
  year: 2005
  ident: WOS:000228195200006
  article-title: Synthesis of beta-peroxy-lactones using 30% H2O2
  publication-title: TETRAHEDRON LETTERS
  doi: 10.1016/j.tetlet.2005.02.158
– volume: 132
  start-page: 807
  year: 2010
  ident: WOS:000275084600060
  article-title: Cyclization of Arylacetoacetates to Indene and Dihydronaphthalene Derivatives in Strong Acids. Evidence for Involvement of Further Protonation of O,O-Diprotonated beta-Ketoester, Leading to Enhancement of Cyclization
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/ja908749u
– volume: 7
  start-page: 5405
  year: 2005
  ident: WOS:000233505700015
  article-title: Synthesis of a 2,3 ';6 ',3 ''-terpyridine scaffold as an alpha-helix mimetic
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol0521228
– volume: 104
  start-page: 4105
  year: 2004
  ident: WOS:000223812900011
  article-title: The Baeyer-Villiger reaction: New developments toward greener procedures
  publication-title: CHEMICAL REVIEWS
  doi: 10.1021/cr030011l
– volume: 16
  start-page: 4280
  year: 2014
  ident: WOS:000340517200057
  article-title: Synthesis of Silyl Monoperoxyketals by Regioselective Cobalt-Catalyzed Peroxidation of Silyl Enol Ethers: Application to the Synthesis of 1,2-Dioxolanes
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol5020015
– volume: 126
  start-page: 107
  year: 1995
  ident: WOS:A1995QE16600013
  article-title: SYNTHESES OF THE TERPENOID PRECURSORS CYCLOPENT-2-ENONE AND CYCLOHEX-2-ENONE DIESTERS
  publication-title: MONATSHEFTE FUR CHEMIE
– volume: 56
  start-page: 4955
  year: 2017
  ident: WOS:000399384700008
  article-title: Stereoelectronic Control in the Ozone-Free Synthesis of Ozonides
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201610699
– volume: 32
  start-page: 1661
  year: 2002
  ident: WOS:000179898500016
  article-title: Antimalarial chemotherapeutic peroxides: artemisinin, yingzhaosu A and related compounds
  publication-title: INTERNATIONAL JOURNAL FOR PARASITOLOGY
– volume: 725
  start-page: 93
  year: 1969
  ident: WOS:A1969D931600011
  article-title: ISOLATION OF DIBENZYL ETHER HYDROPEROXIDE BY PEROXYGENATION OF BENZYL ALCOHOL AND DIBENZYL ETHER
  publication-title: ANNALEN DER CHEMIE-JUSTUS LIEBIG
– volume: 2016
  start-page: 5629
  year: 2016
  ident: WOS:000390760000006
  article-title: Synthesis of the 1,3,4-Oxadiazole Core through Thermolysis of Geminal Diazides
  publication-title: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1002/ejoc.201601119
– volume: 51
  start-page: 4093
  year: 2008
  ident: WOS:000257721600006
  article-title: Chemo-enzymatic synthesis of a series of 2,4-syn-functionalized (S)-glutamate analogues: New insight into the structure-activity relation of ionotropic glutamate receptor subtypes 5, 6, and 7
  publication-title: JOURNAL OF MEDICINAL CHEMISTRY
  doi: 10.1021/jm800092x
– volume: 27
  start-page: 627
  year: 1962
  ident: WOS:A19626277B00074
  article-title: OXIDATION OF ANISOLE AND DIPHENYL ETHER WITH TRIFLUOROPEROXYACETIC ACID
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
– volume: 5
  start-page: 3895
  year: 2007
  ident: WOS:000251274700002
  article-title: alpha-Substituted organic peroxides: synthetic strategies for a biologically important class of gem-dihydroperoxide and perketal derivatives
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/b711647k
– volume: 44
  start-page: 7359
  year: 2003
  ident: WOS:000185605200029
  article-title: A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes
  publication-title: TETRAHEDRON LETTERS
  doi: 10.1016/S0040-4039(03)01844-6
– volume: 7
  start-page: 19506
  year: 2017
  ident: WOS:000399242100013
  article-title: Advances in the synthesis of acyclic peroxides
  publication-title: RSC ADVANCES
  doi: 10.1039/c6ra28489b
– volume: 11
  start-page: 633
  year: 2009
  ident: WOS:000262913500035
  article-title: Mycangimycin, a Polyene Peroxide from a Mutualist Streptomyces sp.
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol802709x
– year: 2009
  ident: 000449443200045.91
  publication-title: Patai Chemistry of Functional Groups
– volume: 139
  start-page: 10799
  year: 2017
  ident: WOS:000407540200035
  article-title: Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular alpha-Effect
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/jacs.7b05367
– volume: 11
  start-page: 2613
  year: 2013
  ident: WOS:000316803900010
  article-title: Phosphomolybdic and phosphotungstic acids as efficient catalysts for the synthesis of bridged 1,2,4,5-tetraoxanes from beta-diketones and hydrogen peroxide
  publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY
  doi: 10.1039/c3ob27239g
– volume: 79
  start-page: 1991
  year: 1957
  ident: WOS:A1957WB80700064
  article-title: THE ACTION OF LEAD TETRAACETATE ON AN ENOL ACETATE - THE EPIMERIC 16-ACETOXY DERIVATIVES OF EPIANDROSTERONE ACETATE, THEIR INTERCONVERSION AND REARRANGEMENT
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 85
  start-page: 222
  year: 1963
  ident: WOS:A19633107B00029
  article-title: STUDIES IN ORGANIC PEROXIDES .29. STRUCTURE OF PEROXIDES DERIVED FROM 2,4-PENTANEDIONE AND HYDROGEN PEROXIDE
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 95
  start-page: 77
  year: 1962
  ident: WOS:A19628506A00031
  article-title: ALKYLPEROXYDE .30. PEROXYDE VON DIKETONEN .1. PEROXYDE DES ACETYLACETONS
  publication-title: CHEMISCHE BERICHTE-RECUEIL
– volume: 6
  start-page: 2539
  year: 2004
  ident: WOS:000222706600013
  article-title: Double- and triple-consecutive O-insertion into tert-butyl and triarylmethyl structures
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol049171p
– volume: 47
  start-page: 4658
  year: 1982
  ident: WOS:A1982PR58400011
  article-title: THERMAL CHEMISTRY OF CYCLOPROPYL-SUBSTITUTED MALONYL PEROXIDES - A NEW CHEMI-LUMINESCENT REACTION
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
– volume: 57
  start-page: 4712
  year: 2018
  ident: WOS:000430165700048
  article-title: Enantioselective N-Heterocyclic Carbene Catalysis via the Dienyl Acyl Azolium
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  doi: 10.1002/anie.201712604
– volume: 31
  start-page: 2259
  year: 1990
  ident: WOS:A1990DB43100011
  article-title: PHOTOOXYGENATION OF 3-SILYLOXYBENZOFURANS AND 2-SILYLOXYBENZOFURANS - REARRANGEMENT OF DIOXETANES VIA ALPHA-SILYLPEROXY KETONES TO KETOESTER CLEAVAGE PRODUCTS
  publication-title: TETRAHEDRON LETTERS
– volume: 137
  start-page: 13744
  year: 2015
  ident: WOS:000364355900006
  article-title: Intramolecular Transfer of Singlet Oxygen
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  doi: 10.1021/jacs.5b07848
– volume: 13
  start-page: 4212
  year: 2011
  ident: WOS:000293759100016
  article-title: A Hydrogen Peroxide Based Access to Qinghaosu (Artemisinin)
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol2015434
– volume: 1999
  start-page: 737
  year: 1999
  ident: WOS:000079499800001
  article-title: 100 years of Baeyer-Villiger oxidations
  publication-title: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
– volume: 54
  start-page: 1214
  year: 2005
  ident: WOS:000233758600022
  article-title: Synthesis of 1,1 '-bishydroperoxydi(cycloalkyl) peroxides by homocoupling of 11-15-membered gem-bis (hydroperoxy)cycloalkanes in the presence of boron trifluoride
  publication-title: RUSSIAN CHEMICAL BULLETIN
– volume: 26
  start-page: 1197
  year: 2015
  ident: WOS:000363908100012
  article-title: Enantioselective biocatalytic reduction of 2,2-disubstituted ethylacetoacetates: an indirect desymmetrization approach for the synthesis of enantiopure (S)-4-hydroxy-3,3-disubstituted pentane-2-ones
  publication-title: TETRAHEDRON-ASYMMETRY
  doi: 10.1016/j.tetasy.2015.09.007
– volume: 32
  start-page: 43
  year: 2013
  ident: WOS:000323387900006
  article-title: PolyVinylPolyPyrrolidone-Supported Boron Trifluoride (PVPP-BF3); Highly Efficient Catalyst for Oxidation of Aldehydes to Carboxylic Acids and Esters by H2O2
  publication-title: IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION
– volume: 14
  start-page: 6849
  year: 2008
  ident: WOS:000258683600003
  article-title: Reaction of epoxyketones with hydrogen peroxide - Ethane-1,1-dihydroperoxide as a surprisingly stable product
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  doi: 10.1002/chem.200800932
– volume: 50
  start-page: 10597
  year: 1994
  ident: WOS:A1994PD85700022
  article-title: TOTAL SYNTHESIS OF (-)-KJELLMANIANONE FROM TRICYCLODECADIENONE - A REVISION OF ITS ABSOLUTE-CONFIGURATION
  publication-title: TETRAHEDRON
– volume: 89
  start-page: 1533
  year: 2011
  ident: WOS:000299012500012
  article-title: Direct benzylation of 1,3-dicarbonyl compounds catalyzed by Cs2.5H0.5PW12O40 in solvent-free conditions
  publication-title: CANADIAN JOURNAL OF CHEMISTRY
  doi: 10.1139/V11-134
– start-page: 2827
  year: 2011
  ident: WOS:000297847700013
  article-title: Phosphomolybdic Acid Catalyzed Synthesis of 1,2,4,5-Tetraoxanes
  publication-title: SYNLETT
  doi: 10.1055/s-0031-1289864
– volume: 2005
  start-page: 4167
  year: 2005
  ident: WOS:000232322700015
  article-title: Intramolecular Heck couplings and cycloisomerizations of bromodienes and enynes with 1 ',1 '-disubstituted methylenecyclopropane terminators: Efficient syntheses of [3]dendralenes
  publication-title: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1002/ejoc.200500330
– volume: 11
  start-page: 2691
  year: 2009
  ident: WOS:000266930900054
  article-title: Facile Ring-Opening of Oxiranes by H2O2 Catalyzed by Phosphomolybdic Acid
  publication-title: ORGANIC LETTERS
  doi: 10.1021/ol900811m
– volume: 112
  start-page: 6965
  year: 1990
  ident: WOS:A1990DY96200034
  article-title: CHEMISTRY OF ALDOLATE DIANIONS - EFFECTS OF BETA-HETEROATOM SUBSTITUENTS ON KETONE ENOLIZATION
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 30
  year: 2017
  ident: WOS:000449443200045.9
  publication-title: J PHYS ORG CHEM
– volume: 60
  start-page: 139
  year: 2011
  ident: WOS:000292212000019
  article-title: Acylation of Meldrum's acid with arylacetic acid imidazolides as a convenient method for the synthesis of 4-aryl-3-oxobutanoates
  publication-title: RUSSIAN CHEMICAL BULLETIN
– volume: 105
  start-page: 7735
  year: 1983
  ident: WOS:A1983RX40100046
  article-title: ANTIFUNGAL PEROXIDE-CONTAINING ACIDS FROM 2 CARIBBEAN SPONGES
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
– volume: 72
  start-page: 3277
  year: 2016
  ident: WOS:000376799800018
  article-title: The first example of catalytic synthesis of N-aryl-substituted tetraoxazaspiroalkanes
  publication-title: TETRAHEDRON
  doi: 10.1016/j.tet.2016.04.055
– start-page: 1289
  year: 1973
  ident: WOS:A1973P142900026
  article-title: BETA-PEROXY-BETA-PROPIOLACTOLS - CYCLIC ANALOGS OF BAEYER-VILLIGER INTERMEDIATE
  publication-title: TETRAHEDRON LETTERS
– volume: 58
  start-page: 3884
  year: 2017
  ident: WOS:000412613600022
  article-title: Synthesis of (-)-okundoperoxide and determination of the absolute configuration of natural (+)-okundoperoxide
  publication-title: TETRAHEDRON LETTERS
  doi: 10.1016/j.tetlet.2017.08.064
– volume: 100
  start-page: 443
  year: 1988
  ident: 000449443200045.5
  article-title: Reduktion von 1,2-Dioxetanen durch Thiole als mogliche Schutzreaktion gegen Photochemische Schadigung der DNA in der Zelle.
  publication-title: Angew. Chem
– volume: 12
  start-page: 1647
  year: 2016
  ident: WOS:000381258800001
  article-title: Rearrangements of organic peroxides and related processes
  publication-title: BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.3762/bjoc.12.162
– volume: 72
  start-page: 6534
  year: 2007
  ident: WOS:000248793400026
  article-title: The effect of iodine on the peroxidation of carbonyl compounds
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo0708745
– volume: 75
  start-page: 7928
  year: 2010
  ident: WOS:000284080300052
  article-title: Gold(I)-Catalyzed Addition of Carboxylic Acids to Alkynes
  publication-title: JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.1021/jo101543q
– start-page: 1347
  year: 1975
  ident: WOS:A1975AM70100010
  article-title: REACTIONS OF SOME DICARBONYL-COMPOUNDS .3. OXIDATION OF SOME BETA-DIKETONES WITH ALKALINE HYDROGEN-PEROXIDE
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
– volume: 22
  start-page: 1203
  year: 1981
  ident: WOS:A1981LG72200009
  article-title: VACUUM FLASH PYROLYSIS (VFP) OF MALONYL PEROXIDES - DECARBOXYLATION VERSUS DECARBONYLATION OF THE INTERMEDIARY ALPHA-LACTONES
  publication-title: TETRAHEDRON LETTERS
– volume: 10
  start-page: 34
  year: 2014
  ident: WOS:000329820200001
  article-title: Synthesis of five- and six-membered cyclic organic peroxides: Key transformations into peroxide ring-retaining products
  publication-title: BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
  doi: 10.3762/bjoc.10.6
– volume: 20
  start-page: 605
  year: 2007
  ident: WOS:000251390500008
  article-title: Artemisinins and synthetic trioxolanes in the treatment of helminth infections
  publication-title: CURRENT OPINION IN INFECTIOUS DISEASES
SSID ssj0000555
Score 2.39636
Snippet We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their...
We have discovered synthetic access to beta-hydroperoxy-beta-peroxylactones via BF3-catalyzed cyclizations of a variety of acyclic precursors, beta-ketoesters...
We have discovered synthetic access to β-hydroperoxy-β-peroxylactones via BF₃-catalyzed cyclizations of a variety of acyclic precursors, β-ketoesters and their...
Source Web of Science
SourceID proquest
webofscience
acs
SourceType Aggregation Database
Enrichment Source
Index Database
Publisher
StartPage 13427
SubjectTerms acetates
chemical structure
Chemistry
Chemistry, Organic
enols
hydrogen peroxide
organic chemistry
oxidation
Physical Sciences
potential energy
roads
Science & Technology
silyl enol ethers
thermodynamics
Title Five Roads That Converge at the Cyclic Peroxy-Criegee Intermediates: BF3‑Catalyzed Synthesis of β‑Hydroperoxy-β-peroxylactones
URI http://dx.doi.org/10.1021/acs.joc.8b02218
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000449443200045
https://www.proquest.com/docview/2125298605
https://www.proquest.com/docview/2220891242
Volume 83
WOS 000449443200045
WOSCitedRecordID wos000449443200045
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3NbtQwELagHODCP-pCqYzUa5Z4_BOHG0RdrSqBEG2l3iL_BQrVbrXJHrYnDrwAr9IH6UPwJIydtAWKoDcrcZyJM-P5xmN_JmTLe53rxpms8YABim1CZizzmeNF2UgOLncxo_v2nZrui50DeXBJFv1nBh_YS-Pa8ee5G2uL7obpm-QWKDThiIKq3ctBV0p5QQwOil-w-FxpILoh1_4GKP_icpJ7mdzrF2a1iZUwrir5Ml52duxOrnI2_l_y--TuADLp614rHpAbYfaQ3K7Oz3Z7RL5NcJCjH-bGt3Tvk-loFRefLz4GimWEhLRauaNDR9-HKE9WLWJqPdA0fZj2miBAfUXfTPiPr9-rOAG0Ogme7q5m-Gx72NJ5Q89O8d505eNkf2rk7DTrS0fxiB8cYR-T_cn2XjXNhvMYMoOG3WWcFx7dl2ZFYZxj4KWXBqBQzAhu0fK1xzidWVNw3QgbNFgQRmHQ5FRwYPgTsjbD9tcJFU4VRprQ2KBQQXItRCmCkZHvPm9KNSJb2Hv1YE9tnVLlwOr-oquHLh2RF-d_scYejLkOMwvzZVujR5YoKgZr_6gDkOsSAQ7g635Vgfq4Z_qoU767FIJDwr4jwq5TrRrY1SOrQPf0el_yjNxBKKbTLkfYIGvdYhmeI9zp7GZS9J8SWP79
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1Lb9QwEB6VciiX8hbL00i9Zkn8SBxuJWK1QFsB3Uq9WX4FSqtdtMketicO_AH-Sn9IfwS_hLE3u-UlVG6W40zGznjmG489BthyTqaytjqpHUUHxdQ-0SZziWVFWQtGbWpDRHd3Lx8e8NeH4nAN0uVZGGSiQUpNDOJfZBfInoW6TxPblwatTiavwFWEIjTI9Ha1f6F7hRCr_OA0Z6tkPn8QCNbINr_gyr9YnmhlBtfh3Yq_uLnkuD9rTd-e_pa68X86cAM2O8hJthcychPW_PgWbFTLm95uw9cBqjzyfqJdQ0YfdUuqsBV9-sETLCNAJNXcnhxZ8tYHtpJqGgLtnsTFxHjyBOHqc_JiwL5_-VaF5aD5qXdkfz7Gd5ujhkxqcn6Gz4ZzF5b-I5Hzs2RROgkX_qC-vQMHg5ejaph0tzMkGqd5mzBWODRmMisKbW1GnXBCU1rkmebMoB6QDr32zOiCyZobL6mhXOfoQtncW6rZXVgfI_17QLjNCy20r43PUVxSyXnJvRYh-31al3kPtnD0VDe7GhUD5zRTi0qruiHtwdPlz1Q4giHyocd-MmsU2meBrKLr9o82lKayRLhD8XM_S4L6vMj7oWL0u-Sc0YiEe5BdplnV5VoPOQba-5fryRPYGI52d9TOq703D-AagjQZzz_Sh7DeTmf-EQKh1jyOsv8Dt2AHbQ
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1Lb9QwELagSNALb9TlaaRes8SvxOFWAtHyqiralXqz_IRCtVttsoftiQN_gL_SH9IfwS9h7E2Xp1C5WY4zGTtjz4zH8xmhTedkLoPVWXAUHBQTfKYNcZllZRUEoza3MaL7drsYjfmrfbHfJ4XFXBhgogVKbQrix1l95EKPMECexPqPUzuUBjQPkRfRpRi0i3K9Ve_-WH-FECuMcFqwFaDPHwSiRrLtL7blX7RP0jTNNTRe8ZgOmHwazjsztMe_wTf-byeuo6u96Ym3lrJyA13wk5voSn1249st9KWBpQ-_m2rX4r0PusN1PJI-e-8xlMFQxPXCHh5YvOMja1k9iwF3j9OmYspAAbP1KX7WsG-fv9ZxW2hx7B3eXUzg3fagxdOAT0_g2WjhYgggETk9yZalw3jxD6y7t9G4ebFXj7L-loZMw3TvMsZKB0pNkrLU1hLqhBOa0rIgmjMD64F04L0To0smAzdeUkO5LsCVsoW3VLM7aG0C9DcQ5rYotdA-GF-A2OSS84p7LSIKfh6qYoA2YfRUP8talQLolKhlpVX9kA7Q47MfqmAEYwRET_x03irQ0wJYBRfuH20ozWUFZg-Fz_0sDepoif-hUhS84pzRZBEPEDlPs7rHXI9YA93d8_XkEbq887xRb15uv76H1sFWkykNkt5Ha91s7h-APdSZh0n8vwMeeAnw
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Five+Roads+That+Converge+at+the+Cyclic+Peroxy-Criegee+Intermediates%3A+BF%E2%82%83-Catalyzed+Synthesis+of+%CE%B2-Hydroperoxy-%CE%B2-peroxylactones&rft.jtitle=Journal+of+organic+chemistry&rft.au=Vil%E2%80%99%2C+Vera+A.&rft.au=Gomes%2C+Gabriel+dos+Passos&rft.au=Ekimova%2C+Maria+V&rft.au=Lyssenko%2C+Konstantin+A&rft.date=2018-11-02&rft.issn=1520-6904&rft.volume=83&rft.issue=21+p.13427-13445&rft.spage=13427&rft.epage=13445&rft_id=info:doi/10.1021%2Facs.joc.8b02218&rft.externalDBID=NO_FULL_TEXT
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0022-3263&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0022-3263&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0022-3263&client=summon