ZnO/Au Composite Nanoarrays As Substrates for Surface-Enhanced Raman Scattering Detection

Well-aligned ZnO nanoneedle and nanorod arrays were grown on an aluminum-doped zinc oxide (AZO) buffer layer by chemical vapor deposition and used as templates for making gold-coated ZnO (ZnO/Au) composite nanoarrays. The coverage of Au nanoparticles on ZnO nanoneedle and nanorod was controlled by v...

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Published inJournal of physical chemistry. C Vol. 114; no. 1; pp. 93 - 100
Main Authors Chen, Limiao, Luo, Linbao, Chen, Zhenhua, Zhang, Mingliang, Zapien, Juan Antonio, Lee, Chun Sing, Lee, Shuit Tong
Format Journal Article
LanguageEnglish
Published American Chemical Society 14.01.2010
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Abstract Well-aligned ZnO nanoneedle and nanorod arrays were grown on an aluminum-doped zinc oxide (AZO) buffer layer by chemical vapor deposition and used as templates for making gold-coated ZnO (ZnO/Au) composite nanoarrays. The coverage of Au nanoparticles on ZnO nanoneedle and nanorod was controlled by varying the concentration of Au precursor. High coverage led to the formation of ZnO/Au nanoneedle bundles. The ZnO/Au composite nanoarrays were applied as substrates in surface-enhanced Raman scattering (SERS) measurement. The SERS enhancement factor is mainly controlled by gold coverage and morphologies of the ZnO/Au nanoarrays. Their application in rapid detection of melamine in egg white is demonstrated. This SERS-based melamine detection is advantageous in that sample pretreatment is not needed. It showed the potential of the ZnO/Au nanoarrays as a convenient and robust SERS-active substrate for food safety monitoring.
AbstractList Well-aligned ZnO nanoneedle and nanorod arrays were grown on an aluminum-doped zinc oxide (AZO) buffer layer by chemical vapor deposition and used as templates for making gold-coated ZnO (ZnO/Au) composite nanoarrays. The coverage of Au nanoparticles on ZnO nanoneedle and nanorod was controlled by varying the concentration of Au precursor. High coverage led to the formation of ZnO/Au nanoneedle bundles. The ZnO/Au composite nanoarrays were applied as substrates in surface-enhanced Raman scattering (SERS) measurement. The SERS enhancement factor is mainly controlled by gold coverage and morphologies of the ZnO/Au nanoarrays. Their application in rapid detection of melamine in egg white is demonstrated. This SERS-based melamine detection is advantageous in that sample pretreatment is not needed. It showed the potential of the ZnO/Au nanoarrays as a convenient and robust SERS-active substrate for food safety monitoring.
Author Luo, Linbao
Zhang, Mingliang
Chen, Limiao
Chen, Zhenhua
Zapien, Juan Antonio
Lee, Chun Sing
Lee, Shuit Tong
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Snippet Well-aligned ZnO nanoneedle and nanorod arrays were grown on an aluminum-doped zinc oxide (AZO) buffer layer by chemical vapor deposition and used as templates...
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SubjectTerms C: Nanops and Nanostructures
Title ZnO/Au Composite Nanoarrays As Substrates for Surface-Enhanced Raman Scattering Detection
URI http://dx.doi.org/10.1021/jp908423v
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