Executing and Rationalizing the Synthesis of a Difluorinated Analogue of a Ring-Expanded Calystegine B2 - Kyne, Sara H; Miles, Jonathan A. L; Percy, Jonathan M; Singh, Kuldip (Journal of organic chemistry, 2012)
Keywords: Chemistry; Chemistry, Organic; Exact sciences and technology; Fluorine Compounds - chemical synthesis; Fluorine Compounds - chemistry; Heterocyclic compounds; Heterocyclic compounds with only one n hetero atom and condensed derivatives; Magnetic Resonance Spectroscopy; methodology; Models, Molecular; Molecular Structure; Nortropanes - chemical synthesis; Nortropanes - chemistry; Organic chemistry; Physical Sciences; Preparations and properties; Science & Technology; Solanaceous Alkaloids - chemical synthesis; Solanaceous Alkaloids - chemistry; stereochemistry; Stereoisomerism; Thermodynamics; TRANSITION; ENERGY; MECHANISM; DIOXIRANE; ASYMMETRIC EPOXIDATION; FLUORINE; DIMETHYLDIOXIRANE; Regioselectivity; Microwave; Selectivity; Ring cleavage; Stereoselectivity; Alkaloid; Thermodynamic control; Cyclization; Steric effect; Epoxidation; Density functional method; Transannular reaction; Chemical synthesis; Protection