Tuning Dimensions of Complexes through Selective In Situ Reaction, Mechanistic Insights into Ni(II)-Catalyzed Br–OH Exchange, Magnetic Properties, and Density Functional Theory Studies

• Published in: Inorganic chemistry Vol. 61; no. 49; pp. 20159 - 20168
• Main Authors: Si, Chang-Dai, Zhang, Jian-Bin, Pan, Feng-Feng, Yan, Xu, Wang, Peng, Xue, Dong-Qian, Li, Xiu-Juan, Liu, Jia-Cheng, Yuan, Kun
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 12.12.2022
• Subjects: Density Functional Theory; Magnetic Phenomena; Models, Molecular; Phthalic Acids

Two coordination polymers (CPs), namely, [Mn3(L)2(4,4′-bipy)2(H2O)2] n (1) and [Ni­(L1)­(1,4-bib)­(H2O)] n (2) (H3L = 5-(3-bromo-4-carboxyphenoxy)­isophthalic acid, H2L1 = 5-(3-hydroxyphenoxy)­isophthalic acid, 4,4′-bpy = 4,4′-bipyridine, and 1,4-bib = 1,4-bis­(1H-imidazol-1-yl)­benzene), were synth...