Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu33 and Peanut-Shaped Cu62 Nanoclusters

Comproportionation reaction of Cu­(II) salt and copper metallic powder in the presence of tert-butylacetylene (tBuCCH) in methanol at room temperature yielded discrete Cu­(I) tert-butylethynide clusters whose identity depended on the particular co-existing anion employed. Introduction of polyoxomol...

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 138; no. 9; pp. 2909 - 2912
Main Authors Zhang, Li-Min, Mak, Thomas C. W
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 09.03.2016
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