Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu33 and Peanut-Shaped Cu62 Nanoclusters
Comproportionation reaction of Cu(II) salt and copper metallic powder in the presence of tert-butylacetylene (tBuCCH) in methanol at room temperature yielded discrete Cu(I) tert-butylethynide clusters whose identity depended on the particular co-existing anion employed. Introduction of polyoxomol...
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Published in | Journal of the American Chemical Society Vol. 138; no. 9; pp. 2909 - 2912 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
09.03.2016
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Online Access | Get full text |
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