Highly Reversible Chevrel Phase Mo6Se8 Cathode with Low Voltage Hysteresis for Rechargeable Aluminum Batteries

Rechargeable aluminum (Al) batteries have attracted considerable interest as potential large-scale energy storage technologies due to the abundance, high theoretical capacity, and high safety of Al. We report here a highly reversible Al-Mo6Se8 prototype cell with low discharge–charge hysteresis (app...

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Published inACS applied materials & interfaces Vol. 15; no. 29; pp. 34698 - 34703
Main Authors Liu, Meng, Lv, Guocheng, Liu, Hao, Zhang, Jian, Liu, Tianming, Kong, Lingchang, Liao, Libing, Guo, Juchen
Format Journal Article
LanguageEnglish
Published American Chemical Society 26.07.2023
Subjects
Energy, Environmental, and Catalysis Applications
reversibility
voltage hysteresis
cycle stability
rechargeable aluminum battery
chevrel phase Mo6Se8
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Abstract Rechargeable aluminum (Al) batteries have attracted considerable interest as potential large-scale energy storage technologies due to the abundance, high theoretical capacity, and high safety of Al. We report here a highly reversible Al-Mo6Se8 prototype cell with low discharge–charge hysteresis (approximately 50 mV under 30 mA g–1 at 50 °C), ultra-flat discharge plateau, and exceptional cycle stability: the reversible capacity retaining at a steady 77 mA h g–1 after more than 1800 cycles. The Al intercalation-extraction mechanism is probed with ex situ and operando XRD techniques, revealing the reversible intercalation reaction from Mo6Se8 to Al4/3Mo6Se8. The stable electrochemical performance and unambiguous intercalation mechanism of the Al-Mo6Se8 system provide an alternative for beyond-lithium battery technologies.
AbstractList Rechargeable aluminum (Al) batteries have attracted considerable interest as potential large-scale energy storage technologies due to the abundance, high theoretical capacity, and high safety of Al. We report here a highly reversible Al-Mo6Se8 prototype cell with low discharge–charge hysteresis (approximately 50 mV under 30 mA g–1 at 50 °C), ultra-flat discharge plateau, and exceptional cycle stability: the reversible capacity retaining at a steady 77 mA h g–1 after more than 1800 cycles. The Al intercalation-extraction mechanism is probed with ex situ and operando XRD techniques, revealing the reversible intercalation reaction from Mo6Se8 to Al4/3Mo6Se8. The stable electrochemical performance and unambiguous intercalation mechanism of the Al-Mo6Se8 system provide an alternative for beyond-lithium battery technologies.
Author Liu, Hao
Zhang, Jian
Guo, Juchen
Liao, Libing
Kong, Lingchang
Lv, Guocheng
Liu, Tianming
Liu, Meng
AuthorAffiliation Department of Chemical and Environmental Engineering
Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology
China University of Geosciences Beijing
China University of Geosciences
School of Science
University of CaliforniaRiverside
Materials Science and Engineering Program
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– name: Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology
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Issue 29
Keywords reversibility
voltage hysteresis
cycle stability
rechargeable aluminum battery
chevrel phase Mo6Se8
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Title Highly Reversible Chevrel Phase Mo6Se8 Cathode with Low Voltage Hysteresis for Rechargeable Aluminum Batteries
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