Solid-State Diode-like Chemiluminescence Based on Serial, Immobilized Concentration Gradients in Mixed-Valent Poly[Ru(vbpy)3](PF6)2 Films

• Published in: Journal of the American Chemical Society Vol. 118; no. 43; pp. 10609 - 10616
• Main Authors: Maness, Karolyn M, Terrill, Roger H, Meyer, Thomas J, Murray, Royce W, Wightman, R. Mark
• Format: Journal Article
• Language: English
• Published: American Chemical Society 30.10.1996

The electronic conductivity and electrogenerated chemiluminescence (ECL) of thin, electropolymerized films of the fixed-site redox polymer poly[Ru(vbpy)3](PF6)2 (vbpy = 4-vinyl-4‘-methyl-2,2‘-bipyridine) on Pt interdigitated array electrodes were examined for both solvent-swollen and dry films. In b...