Organic Solar Cells Materials Design, Technology and Commercialization

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Main Author Ding, Liming
Format eBook
LanguageEnglish
Published Newark John Wiley & Sons, Incorporated 2022
Edition1
Subjects
Materials science
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Author Ding, Liming
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SubjectTerms Materials science
Subtitle Materials Design, Technology and Commercialization
TableOfContents 12.2 The Characteristics of Indoor Lighting Sources
9.3.1 Morphological Studies of the Molecular Dyads in SCOSCs -- 9.3.2 Morphological Studies of the Block Copolymers in SCOSCs -- 9.3.3 Morphological Studies of the Double‐Cable Polymers in SCOSCs -- 9.4 Perspective and Challenges of SCOSCs -- References -- Chapter 10 Tandem Organic Solar Cells: Recent Progress and Challenge -- 10.1 Introduction -- 10.2 Active Layer Materials in Tandem OSCs -- 10.2.1 Tandem OSCs Based on Fullerene Acceptors -- 10.2.2 Tandem OSCs Based on Non‐fullerene Acceptors -- 10.3 Interconnecting Layer Materials -- 10.4 The Semi‐Empirical Analysis of Tandem OSCs -- 10.5 Conclusion and Outlook -- Acknowledgments -- References -- Chapter 11 Large‐Area Flexible Organic Solar Cells -- 11.1 Introduction -- 11.2 Material Requirements for Large‐Area Flexible Organic Solar Cells -- 11.2.1 Fullerene‐Based Binary System -- 11.2.2 Non‐fullerene‐Based Binary System -- 11.2.3 Ternary System -- 11.2.4 All‐Polymer‐Based System -- 11.2.5 Design Strategies of the Materials for Large‐Area Devices -- 11.3 Flexible Electrodes and Substrates -- 11.3.1 Flexible Substrates -- 11.3.2 Flexible Transparent Electrode Designs -- 11.3.2.1 Conducting Polymers -- 11.3.2.2 Carbon Nanotubes -- 11.3.2.3 Graphene -- 11.3.2.4 Metallic Nanowires -- 11.3.2.5 Hybrid Films -- 11.4 Large‐Area Flexible Device Fabrication -- 11.4.1 Coating and Printing Methods -- 11.4.1.1 Blade Coating -- 11.4.1.2 Slot‐Die Coating -- 11.4.1.3 Inkjet Printing -- 11.4.1.4 Spray Coating -- 11.4.1.5 Screen Printing, Relief Printing, and Gravure Printing -- 11.4.2 R2R Methodology -- 11.5 Efficiency Loss in Large‐Area Devices and Modules -- 11.5.1 Electrical Loss -- 11.5.2 Geometric Loss -- 11.5.3 Optical Loss -- 11.5.4 Additional Loss -- 11.5.5 Modular Designs -- 11.6 Conclusion and Outlook -- References -- Chapter 12 Organic Photovoltaics for Indoor Applications -- 12.1 Introduction
2.3.2.1 Dithienosilole‐Based D1‐A‐D2‐A‐D1‐Type Molecular Donors -- 2.3.2.2 Benzodithiophene‐Based D1‐A‐D2‐A‐D1‐Type Molecular Donors -- 2.3.2.3 Indacenodithiophene‐Based D1‐A‐D2‐A‐D1‐Type Molecular Donors -- 2.3.3 Porphyrin‐Based Molecular Donors -- 2.3.4 Other Molecular Donors -- 2.4 Current Progress on Small‐Molecule Solar Cells with Nonfullerene Acceptors -- 2.4.1 Binary Solar Cells -- 2.4.2 Ternary Solar Cells -- 2.5 Summary and Outlook -- References -- Chapter 3 Fullerene Acceptors -- 3.1 Introduction -- 3.2 Fullerene Acceptors for Organic Solar Cells -- 3.2.1 Pristine Fullerenes -- 3.2.2 Fullerene Monoadducts -- 3.2.2.1 [2+1] Addition Derivatives -- 3.2.2.2 [2+2] Addition Derivatives -- 3.2.2.3 [2+3] Addition Derivatives -- 3.2.2.4 [2+4] Addition Derivatives -- 3.2.2.5 1,4‐Addition Derivatives -- 3.2.3 Fullerene Bisadducts -- 3.2.4 Fullerene Multiadducts -- 3.2.5 Unconventional Fullerenes -- 3.3 Summary -- References -- Chapter 4 Non‐fullerene Small‐Molecule Acceptors for Organic Solar Cells -- 4.1 Molecular Design Principles -- 4.2 PDI‐Based SMAs -- 4.2.1 PDI Monomers -- 4.2.2 PDI Dimers -- 4.2.3 PDI Trimers -- 4.2.4 PDI Tetramers -- 4.3 A-D-A‐Type SMAs -- 4.3.1 Side Chains Optimization -- 4.3.2 End Groups Engineering -- 4.3.3 Core Units Engineering -- 4.3.3.1 IDTT and Its Derivations -- 4.3.3.2 Spacer Unit Effects -- 4.3.3.3 Asymmetric Cores -- 4.3.3.4 Non‐fused Cores -- 4.4 A-DA′D-A-Type SMAs -- 4.4.1 BTA‐Based A-DA′D-A SMAs -- 4.4.2 BT‐Based A-DA′D-A SMAs -- 4.4.3 BSe‐ and Qx‐Based OSCs -- References -- Chapter 5 Electron‐Donating Ladder‐Type Heteroacenes for Photovoltaic Applications: From Polymer Donor Materials to Small‐Molecule Acceptor Materials -- 5.1 Introduction -- 5.2 D-A Copolymers Based on Ladder‐Type Heteroacenes -- 5.2.1 Pentacyclic and Hexacyclic Heteroacenes‐Based D-A Copolymers -- 5.2.2 Heptacene‐Based D-A Copolymers
7.3.1 Progress of N2200 and Its Derivative‐Based All‐PSCs -- 7.3.1.1 Molecular Design Strategy for N2200 Derivatives -- 7.3.1.2 Molecular Design Strategy for PDI Polymers -- 7.3.1.3 Molecular Design Strategy for BTI Polymers -- 7.3.1.4 BTI Polymers for High‐Performance All‐PSCs with Small Eloss -- 7.3.2 Progress of Polymer Acceptors Containing B←N Unit -- 7.3.2.1 Principle of B←N Unit -- 7.3.2.2 Electron‐Deficient Building Blocks Based on B←N Unit -- 7.3.2.3 Optimizing ELUMO -- 7.3.2.4 Tuning Absorption Spectra -- 7.3.2.5 Enhancing Electron Mobility -- 7.3.2.6 Optimizing Active Layer Morphology -- 7.3.3 Progress of Polymer Acceptors Bearing Cyano Groups -- 7.4 Device Performance and Stability of All‐PSCs -- 7.4.1 Morphology Optimization and Device Engineering -- 7.4.2 The Enhanced Stability of All‐PSCs -- 7.4.2.1 Thermal Stability -- 7.4.2.2 Ambient Stability -- 7.4.2.3 Mechanical Stability -- 7.4.2.4 Photostability -- 7.5 Conclusion and Outlook -- References -- Chapter 8 Organic Solar Cells with High Open‐Circuit Voltage &gt -- 1 V -- 8.1 Introduction -- 8.2 n‐Type Small‐Molecule Acceptors -- 8.2.1 Fullerene‐Based SMAs -- 8.2.2 Non‐fullerene SMAs -- 8.2.2.1 PDI‐Based SMAs -- 8.2.2.2 IC and Its Derivatives‐Based A-D-A‐Type SMAs -- 8.2.2.3 A2‐A1‐D‐A1‐A2‐Type SMAs with BT as A1 Units -- 8.2.2.4 A2‐A1‐D‐A1‐A2‐Type SMAs with BTA or Qx as A1 Units -- 8.3 n‐Type Polymers -- 8.4 Conclusion and Outlook -- References -- Chapter 9 Single‐Component Organic Solar Cells -- 9.1 Introduction -- 9.2 Single‐Component Conjugated Materials for SCOSCs -- 9.2.1 Molecular Dyads -- 9.2.1.1 Fullerene‐Based "In‐Chain" Molecular Dyads -- 9.2.1.2 Fullerene‐Based "Side‐Chain" D-A Molecular Dyads -- 9.2.1.3 PBI‐Based Molecular Dyads -- 9.2.2 Block Copolymers -- 9.2.3 Double‐Cable Conjugated Polymers -- 9.3 Morphological Studies of the Photo‐Active Layers in the SCOSCs
Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Conjugated Polymer Donors for Organic Solar Cells -- 1.1 Introduction -- 1.2 LBG Polymers -- 1.2.1 LBG Polymers Based on Benzothiadiazole (BT) -- 1.2.2 LBG Polymers Based on Isoindigo (IID) -- 1.2.3 LBG Polymers Based on Diketopyrrolopyrrole (DPP) -- 1.3 MBG Polymers -- 1.3.1 MBG Polymers Based on Benzothiadiazole (BT) -- 1.3.2 MBG Polymers Based on Quinoxaline (Qx) -- 1.3.3 MBG Polymers Based on Thienopyrrolodione (TPD) -- 1.3.4 MBG Polymers Based on Thieno[3,4‐b]thiophene (TT) -- 1.4 WBG Polymers -- 1.4.1 WBG Polymers Based on Polythiophene (PT) Derivatives -- 1.4.2 WBG Polymers Based on Benzodithiophene‐alt‐Thiophene Derivatives -- 1.4.3 WBG Polymers Based on Benzothiadiazole (BT) Derivatives -- 1.4.4 WBG Polymers Based on Benzotriazole (BTA) Derivatives -- 1.4.5 WBG Polymers Based on Thiazole, Pyrazine, and Their Derivatives Containing N‐Heterocycles -- 1.4.6 WBG Polymers Based on Benzodithiophene‐4,8‐dione (BDD) Derivatives -- 1.4.7 Other WBG Polymers -- 1.5 Summary and Outlook -- References -- Chapter 2 p‐Type Molecular Photovoltaic Materials -- 2.1 Introduction -- 2.2 p‐Type Molecular Photovoltaic Materials Used in Vacuum‐Deposited Solar Cells -- 2.2.1 Oligothiophene‐Based Molecular Donors -- 2.2.2 D‐A‐A′‐Type Molecular Donors -- 2.2.3 Borondipyrromethenes‐Based Molecular Donors -- 2.2.4 Other Molecular Donors -- 2.3 p‐Type Molecular Photovoltaic Materials Used in Solution‐Processed Solar Cells -- 2.3.1 A-D-A‐Type Molecular Donors -- 2.3.1.1 Oligothiophene‐Based A-D-A‐Type Molecular Donors -- 2.3.1.2 Benzodithiophene‐Based A-D-A‐Type Molecular Donors -- 2.3.1.3 Dithienosilole‐Based A-D-A‐Type Molecular Donors -- 2.3.1.4 Dithienopyrrole‐Based A-D-A‐Type Molecular Donors -- 2.3.2 D1‐A‐D2‐A‐D1‐Type Molecular Donors
5.2.3 D-A Copolymers Based on Heteroacenes with Nine or More Fused Rings -- 5.3 A-D-A NFAs Based on Ladder‐Type Heteroacenes -- 5.3.1 A-D-A NFAs Based on Heteropentacenes and Heterohexacenes -- 5.3.2 A-D-A NFAs Based on Heteroheptacenes -- 5.3.2.1 NFAs Based on Heteroheptacenes with sp3‐Hybridized Bridging Atoms -- 5.3.2.2 NFAs Based on Heteroheptacenes Without sp3‐Hybridized Bridging Atoms -- 5.3.3 A-D-A NFAs Based on Heteroacenes with Eight or More Fused Rings -- 5.3.4 Other NFAs -- 5.4 Conclusions and Outlook -- References -- Chapter 6 Chlorinated Organic Solar Cells -- 6.1 Introduction -- 6.2 Chlorination Versus Fluorination: A Comprehensive Study -- 6.2.1 Synthesis -- 6.2.2 The Manipulation of Energy Level and Absorption -- 6.2.3 The Steric Hindrance and Morphology -- 6.2.4 The Synergistic Effect of Chlorination and Fluorination -- 6.3 Recent Advances in Chlorinated Semiconductors -- 6.3.1 Chlorination on the Donor Units of Polymer Donors -- 6.3.1.1 Chlorination of the Donor Units in Backbone of Polymer Donors -- 6.3.1.2 Chlorination of the Donor Units in Side Chain of Polymer Donors -- 6.3.2 Chlorination on the Acceptor Units of Polymer Donors -- 6.3.3 Chlorination of the π‐Bridge of the Polymer Donors -- 6.3.4 Chlorinated Small Molecular Donors -- 6.3.5 Chlorinated Small Molecular Acceptors -- 6.3.5.1 Photovoltaic Performance of Chlorinated Small Molecular Acceptors -- 6.3.5.2 The Investigation of the Crystal Structure of Chlorinated Small Molecular Acceptors -- 6.3.5.3 The Semitransparent Organic Solar Cells Based on Chlorinated Small Molecular Acceptors -- 6.4 Conclusion and Outlook -- References -- Chapter 7 Polymer-Polymer Solar Cells: Materials, Device, and Stability -- 7.1 Introduction -- 7.2 The Device Structure and Basic Principles of All‐PSCs -- 7.3 Materials Design Toward Efficient All‐PSCs
Title Organic Solar Cells
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