Synthetic Studies on Enantioselective Total Synthesis of Cyathane Diterpenoids: Cyrneines A and B, Glaucopine C, and (+)-Allocyathin B2

• Published in: Journal of organic chemistry Vol. 84; no. 6; pp. 3223 - 3238
• Main Authors: Wu, Guo-Jie, Zhang, Yuan-He, Tan, Dong-Xing, He, Long, Cao, Bao-Chen, He, Yu-Peng, Han, Fu-She
• Format: Journal Article
• Language: English
• Published: American Chemical Society 15.03.2019

The details for the synthetic studies on enantioselective total synthesis of cyathane diterpenoids cyrneine A (1) and B (2), glaucopine C (3), and (+)-allocyathin B2 are presented. We established a mild Suzuki coupling for heavily substituted nonactivated cyclopentenyl triflates using a phosphinamid...