Competing Magnetic Interactions in a Dinuclear Ni(II) Complex:  Antiferromagnetic O−H···O Moiety and Ferromagnetic N3 - Ligand

Synthesis, structural characteristics, magnetic studies and DFT calculations in Ni(II) dinuclear complexes containing two bridging N3 - and an O−H···O linkage reveal the existence of ferromagnetic interactions between Ni(II) centers via N3 - ligands and antiferromagntic interactions through the H-bo...

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Published inThe journal of physical chemistry. B Vol. 110; no. 1; pp. 12 - 15
Main Authors Sarkar, Sumana, Datta, Ayan, Mondal, Amrita, Chopra, Deepak, Ribas, Joan, Rajak, Kajal Krishna, Sairam, Pati, Swapan K
Format Journal Article
LanguageEnglish
Published American Chemical Society 12.01.2006
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Abstract Synthesis, structural characteristics, magnetic studies and DFT calculations in Ni(II) dinuclear complexes containing two bridging N3 - and an O−H···O linkage reveal the existence of ferromagnetic interactions between Ni(II) centers via N3 - ligands and antiferromagntic interactions through the H-bonded moiety. The overall magnetic behavior of the system depends on the delicate balance between these two competing interactions.
AbstractList Synthesis, structural characteristics, magnetic studies and DFT calculations in Ni(II) dinuclear complexes containing two bridging N3 - and an O−H···O linkage reveal the existence of ferromagnetic interactions between Ni(II) centers via N3 - ligands and antiferromagntic interactions through the H-bonded moiety. The overall magnetic behavior of the system depends on the delicate balance between these two competing interactions.
Author Pati, Swapan K
Rajak, Kajal Krishna
Mondal, Amrita
Sairam
Sarkar, Sumana
Datta, Ayan
Chopra, Deepak
Ribas, Joan
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Title Competing Magnetic Interactions in a Dinuclear Ni(II) Complex:  Antiferromagnetic O−H···O Moiety and Ferromagnetic N3 - Ligand
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