A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance
A new anhydrous rare-earth metal iodate fluoride, Ce(IO3)2F2, was rationally designed and synthesized. Ce(IO3)2F2 features unique zigzag ∞[CeF2]2+ chains that are bridged by IO3 – groups, creating a complex three-dimensional structure, which is conducive to the orderly arrangement of the lone pair...
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| Published in | Chemistry of materials Vol. 33; no. 8; pp. 2894 - 2900 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
27.04.2021
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| Online Access | Get full text |
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| Abstract | A new anhydrous rare-earth metal iodate fluoride, Ce(IO3)2F2, was rationally designed and synthesized. Ce(IO3)2F2 features unique zigzag ∞[CeF2]2+ chains that are bridged by IO3 – groups, creating a complex three-dimensional structure, which is conducive to the orderly arrangement of the lone pair of the functional IO3 – groups and reinforcing the polarity compared to the hydrous material Ce(IO3)2F2(H2O). Ce(IO3)2F2 possesses a large second-harmonic-generation effect that is ∼5.5 times larger than that of the benchmark KH2PO4, a wide transmission range of 0.45–11.4 μm, and a high laser damage threshold (116.8 MW cm–2). Anhydrous Ce(IO3)2F2 is superior to the hydrous material and is a potential nonlinear optical material. |
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| AbstractList | A new anhydrous rare-earth metal iodate fluoride, Ce(IO3)2F2, was rationally designed and synthesized. Ce(IO3)2F2 features unique zigzag ∞[CeF2]2+ chains that are bridged by IO3 – groups, creating a complex three-dimensional structure, which is conducive to the orderly arrangement of the lone pair of the functional IO3 – groups and reinforcing the polarity compared to the hydrous material Ce(IO3)2F2(H2O). Ce(IO3)2F2 possesses a large second-harmonic-generation effect that is ∼5.5 times larger than that of the benchmark KH2PO4, a wide transmission range of 0.45–11.4 μm, and a high laser damage threshold (116.8 MW cm–2). Anhydrous Ce(IO3)2F2 is superior to the hydrous material and is a potential nonlinear optical material. |
| Author | Mao, Jiang-Gao Zhang, Xiao-Han Huang, Qian-Ming Hu, Chun-Li Chen, Jin Yang, Bing-Ping |
| AuthorAffiliation | State Key Laboratory of Structural Chemistry Fujian Normal University College of Chemistry and Materials Science |
| AuthorAffiliation_xml | – name: Fujian Normal University – name: State Key Laboratory of Structural Chemistry – name: College of Chemistry and Materials Science |
| Author_xml | – sequence: 1 givenname: Xiao-Han surname: Zhang fullname: Zhang, Xiao-Han organization: State Key Laboratory of Structural Chemistry – sequence: 2 givenname: Bing-Ping orcidid: 0000-0003-1743-7658 surname: Yang fullname: Yang, Bing-Ping email: ybp@fjirsm.ac.cn organization: State Key Laboratory of Structural Chemistry – sequence: 3 givenname: Chun-Li surname: Hu fullname: Hu, Chun-Li organization: State Key Laboratory of Structural Chemistry – sequence: 4 givenname: Jin orcidid: 0000-0003-2439-7535 surname: Chen fullname: Chen, Jin organization: State Key Laboratory of Structural Chemistry – sequence: 5 givenname: Qian-Ming surname: Huang fullname: Huang, Qian-Ming organization: State Key Laboratory of Structural Chemistry – sequence: 6 givenname: Jiang-Gao orcidid: 0000-0002-5101-8898 surname: Mao fullname: Mao, Jiang-Gao email: mjg@fjirsm.ac.cn organization: State Key Laboratory of Structural Chemistry |
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| Copyright | 2021 American Chemical Society |
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| DOI | 10.1021/acs.chemmater.1c00222 |
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| Snippet | A new anhydrous rare-earth metal iodate fluoride, Ce(IO3)2F2, was rationally designed and synthesized. Ce(IO3)2F2 features unique zigzag ∞[CeF2]2+ chains... |
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| Title | A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance |
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