Excellent Electrocaloric and Energy Storage Capabilities in (Na0.8K0.2)0.5Bi0.5TiO3 Ceramic

• Published in: ACS applied electronic materials Vol. 5; no. 10; pp. 5722 - 5734
• Main Authors: Varade, Pravin, Pandey, Adityanarayan H., Sowmya, Nelaballi Shara, Gupta, Surya Mohan, Bhisikar, Abhay, Venkataramani, Narayanan, Kulkarni, Ajit R.
• Format: Journal Article
• Language: English
• Published: American Chemical Society 24.10.2023
• Subjects: electrocaloric effect; relaxor ferroelectric; electrical energy storage; morphotropic phase boundary; polar nanoregions
• ISSN: 2637-6113; 2637-6113
• DOI: 10.1021/acsaelm.3c01063

A temperature-dependent polarization switching study reveals a normal ferroelectric P–E loop to an antiferroelectric double hysteresis loop in the vicinity of depolarization temperature (400 K, T d), which is believed to show a strong electrocaloric effect (ECE) and electrical energy-storage density (W rec) in (Na0.8K0.2)0.5Bi0.5TiO3 (NKBT) ceramic when measured by an indirect method. Structural analysis using X-ray diffraction, Raman spectroscopy, and transmission electron microscopy studies confirmed the coexistence of tetragonal (P4mm) and rhombohedral (R3c) phases. A temperature-dependent dielectric study has revealed a frequency dispersion around 400 K, which hints at the presence of a frustrated interaction resulting in the slowing down of polar domain dynamics below a diffuse phase transition. The high value of ECE in the lead-free NKBT ceramic is also investigated by a direct method, confirming the multifunctional nature of NKBT and its usefulness for applications in refrigeration and energy storage. A direct method of electrocaloric (EC) measurement in NKBT ceramic exhibits an adiabatic temperature change (ΔT) ∼ 1.10 K and an EC strength (ξ) ∼ 0.55 Kmm/kV near T d at an externally applied field of 20 kV/cm, which is consistent with the literature. The recoverable energy (W rec) ∼ 0.78 J/cm3 and electrical storage efficiency (η) ∼ 86% are also observed near T d when an applied field of 20 kV/cm is switched at 1 Hz. This behavior is ascribed to the delicate balance between the field-induced normal ferroelectric–antiferroelectric transition and the thermal energy needed to disrupt the frustrated interaction.