Solvent-Controlled Synthesis of Zn–Co–S@Ni12P5 Arrays with Ultra-High Specific Capacitance for Hybrid Supercapacitor
The solvents used in the preparation process have a substantial influence on the structure and morphology of electrode materials, which in turn can impact the electrochemical performance for the supercapacitor. In this work, nickel foam substrate was subjected to a low-temperature phosphating reacti...
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Published in | ACS applied electronic materials Vol. 6; no. 5; pp. 3297 - 3303 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
28.05.2024
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Subjects | |
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Abstract | The solvents used in the preparation process have a substantial influence on the structure and morphology of electrode materials, which in turn can impact the electrochemical performance for the supercapacitor. In this work, nickel foam substrate was subjected to a low-temperature phosphating reaction and then transition metal sulfides were controlled grown on the surface of Ni12P5/NF with different morphology by tuning the ratios of reaction solvents (H2O: C2H5OH). The optimized Zn–Co–S@Ni12P5/NF-1 nanosheet has an ultrahigh specific capacitance (10.7 F cm–2 at 1 mA cm–2), which originates from both the special nanosheet structure with an abundance of active sites, as well as the synergistic interaction between metal sulfides and phosphides. The assembled hybrid supercapacitor (HSC) device (Zn–Co–S@Ni12P5/NF-1//AC) has a high storage capacity (40.11 Wh/kg at 803.09 W/kg) and maintains 85.2% retention rate after 5,000 cycles. Moreover, the all-solid hybrid supercapacitors effectively lit up 9 LEDs for 2 min, which means it holds significant promise for practical energy storage applications. |
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AbstractList | The solvents used in the preparation process have a substantial influence on the structure and morphology of electrode materials, which in turn can impact the electrochemical performance for the supercapacitor. In this work, nickel foam substrate was subjected to a low-temperature phosphating reaction and then transition metal sulfides were controlled grown on the surface of Ni12P5/NF with different morphology by tuning the ratios of reaction solvents (H2O: C2H5OH). The optimized Zn–Co–S@Ni12P5/NF-1 nanosheet has an ultrahigh specific capacitance (10.7 F cm–2 at 1 mA cm–2), which originates from both the special nanosheet structure with an abundance of active sites, as well as the synergistic interaction between metal sulfides and phosphides. The assembled hybrid supercapacitor (HSC) device (Zn–Co–S@Ni12P5/NF-1//AC) has a high storage capacity (40.11 Wh/kg at 803.09 W/kg) and maintains 85.2% retention rate after 5,000 cycles. Moreover, the all-solid hybrid supercapacitors effectively lit up 9 LEDs for 2 min, which means it holds significant promise for practical energy storage applications. |
Author | Tao, Kai Zhan, Huixin Huang, Shijie Han, Lei Li, Guochang Zhao, Wenna |
AuthorAffiliation | School of Materials Science and Chemical Engineering Ningbo Customs District Technology Center School of Biological and Chemical Engineering |
AuthorAffiliation_xml | – name: School of Materials Science and Chemical Engineering – name: Ningbo Customs District Technology Center – name: School of Biological and Chemical Engineering |
Author_xml | – sequence: 1 givenname: Huixin surname: Zhan fullname: Zhan, Huixin organization: School of Materials Science and Chemical Engineering – sequence: 2 givenname: Shijie surname: Huang fullname: Huang, Shijie organization: Ningbo Customs District Technology Center – sequence: 3 givenname: Guochang surname: Li fullname: Li, Guochang organization: School of Materials Science and Chemical Engineering – sequence: 4 givenname: Kai orcidid: 0000-0001-8177-0696 surname: Tao fullname: Tao, Kai organization: School of Materials Science and Chemical Engineering – sequence: 5 givenname: Wenna surname: Zhao fullname: Zhao, Wenna email: wnzhao@nbt.edu.cn organization: School of Biological and Chemical Engineering – sequence: 6 givenname: Lei orcidid: 0000-0002-2433-9290 surname: Han fullname: Han, Lei email: hanlei@nbu.edu.cn organization: School of Materials Science and Chemical Engineering |
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Keywords | Supercapacitor hydrothermal metal sulfide morphology hybrid electrode metal phosphide |
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Title | Solvent-Controlled Synthesis of Zn–Co–S@Ni12P5 Arrays with Ultra-High Specific Capacitance for Hybrid Supercapacitor |
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