Fluxional Processes in Asymmetric Hydroformylation Catalysts [HRhL⌒L(CO)2] Containing C 2-Symmetric Diphosphite Ligands

• Published in: Organometallics Vol. 16; no. 26; pp. 5681 - 5687
• Main Authors: Buisman, Godfried J. H, van der Veen, Lars A, Kamer, Paul C. J, van Leeuwen, Piet W. N. M
• Format: Journal Article
• Language: English
• Published: American Chemical Society 23.12.1997

Solution structures of hydridorhodium diphosphite dicarbonyl complexes [HRhL⌒L1 - 9(CO)2] have been studied. Diphosphites L⌒L1 to L⌒L9 are based on C 2 symmetric (2R,3R)-butane-2,3-diol, (2R,3R)-diethyl tartrate, (2R,4R)-pentane-2,4-diol, and (2S,5S)-hexane-2,5-diol backbones substituted with 1,1‘-b...