Sustainable Solvents in Metallaphotoredox Catalysis
Metallaphotoredox chemistry has emerged as a powerful tool to access synthetically challenging motifs in a rapid and efficient manner. Generally, photoredox catalysis is recognized as a green technology, avoiding highly reactive chemicals and using ambient temperatures. Nevertheless, solvent choice...
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Published in | ACS sustainable chemistry & engineering Vol. 12; no. 24; pp. 8998 - 9002 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
31.05.2024
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Subjects | |
Online Access | Get full text |
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Abstract | Metallaphotoredox chemistry has emerged as a powerful tool to access synthetically challenging motifs in a rapid and efficient manner. Generally, photoredox catalysis is recognized as a green technology, avoiding highly reactive chemicals and using ambient temperatures. Nevertheless, solvent choice is often overlooked with commonly used hazardous sulfoxides, ethers, and amides such as DMF or DMAc. Herein, we emphasize the importance of sustainable solvents in photoredox chemistry and their application to process chemistry. We present alternative conditions for two of the most utilized photocatalytic reactions in the pharmaceutical industry. |
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AbstractList | Metallaphotoredox chemistry has emerged as a powerful tool to access synthetically challenging motifs in a rapid and efficient manner. Generally, photoredox catalysis is recognized as a green technology, avoiding highly reactive chemicals and using ambient temperatures. Nevertheless, solvent choice is often overlooked with commonly used hazardous sulfoxides, ethers, and amides such as DMF or DMAc. Herein, we emphasize the importance of sustainable solvents in photoredox chemistry and their application to process chemistry. We present alternative conditions for two of the most utilized photocatalytic reactions in the pharmaceutical industry. |
Author | Fernández, David F. Knauber, Thomas Bohlke, Joseph González-Esguevillas, María Armstrong, Cameron |
AuthorAffiliation | Pfizer Inc Medicine Design Chemical Research and Development |
AuthorAffiliation_xml | – name: Pfizer Inc – name: Chemical Research and Development – name: Medicine Design |
Author_xml | – sequence: 1 givenname: Joseph surname: Bohlke fullname: Bohlke, Joseph organization: Chemical Research and Development – sequence: 2 givenname: Cameron orcidid: 0000-0001-6342-0860 surname: Armstrong fullname: Armstrong, Cameron organization: Chemical Research and Development – sequence: 3 givenname: Thomas orcidid: 0000-0002-3354-3322 surname: Knauber fullname: Knauber, Thomas organization: Pfizer Inc – sequence: 4 givenname: María orcidid: 0000-0003-3779-5516 surname: González-Esguevillas fullname: González-Esguevillas, María email: maria.gonzalezesguevillas@pfizer.com organization: Chemical Research and Development – sequence: 5 givenname: David F. orcidid: 0000-0003-3482-0894 surname: Fernández fullname: Fernández, David F. email: david.fernandezfernandez@pfizer.com organization: Chemical Research and Development |
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Keywords | Sustainable Solvents Cross-Electrophile Coupling Decarboxylative Arylation Photocatalysis |
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