Derivatized polyoxomolybdates. Synthesis and characterization of oxomolybdate clusters containing coordinatively bound diazenido units. Crystal and molecular structure of the octanuclear oxomolybdate (NHEt3)2(n-Bu4N)2[Mo8O20(NNPh)6] and comparison to the structures of the parent oxomolybdate .alpha.-(n-Bu4N)4[Mo8O26] and the tetranuclear (diazenido)oxomolybdates (n-Bu4N)2[Mo4O10(OMe)2(NNPh)2] and (n-Bu4N)2[Mo4O8(OMe)2(NNC6H4NO2)4]
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Published in | Inorganic chemistry Vol. 26; no. 24; pp. 4079 - 4089 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
01.12.1987
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Online Access | Get full text |
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Author | Hsieh, Tze Chen Zubieta, Jon Shaikh, Shahid N |
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Title | Derivatized polyoxomolybdates. Synthesis and characterization of oxomolybdate clusters containing coordinatively bound diazenido units. Crystal and molecular structure of the octanuclear oxomolybdate (NHEt3)2(n-Bu4N)2[Mo8O20(NNPh)6] and comparison to the structures of the parent oxomolybdate .alpha.-(n-Bu4N)4[Mo8O26] and the tetranuclear (diazenido)oxomolybdates (n-Bu4N)2[Mo4O10(OMe)2(NNPh)2] and (n-Bu4N)2[Mo4O8(OMe)2(NNC6H4NO2)4] |
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