Derivatized polyoxomolybdates. Synthesis and characterization of oxomolybdate clusters containing coordinatively bound diazenido units. Crystal and molecular structure of the octanuclear oxomolybdate (NHEt3)2(n-Bu4N)2[Mo8O20(NNPh)6] and comparison to the structures of the parent oxomolybdate .alpha.-(n-Bu4N)4[Mo8O26] and the tetranuclear (diazenido)oxomolybdates (n-Bu4N)2[Mo4O10(OMe)2(NNPh)2] and (n-Bu4N)2[Mo4O8(OMe)2(NNC6H4NO2)4]

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Published inInorganic chemistry Vol. 26; no. 24; pp. 4079 - 4089
Main Authors Hsieh, Tze Chen, Shaikh, Shahid N, Zubieta, Jon
Format Journal Article
LanguageEnglish
Published American Chemical Society 01.12.1987
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Author Hsieh, Tze Chen
Zubieta, Jon
Shaikh, Shahid N
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Title Derivatized polyoxomolybdates. Synthesis and characterization of oxomolybdate clusters containing coordinatively bound diazenido units. Crystal and molecular structure of the octanuclear oxomolybdate (NHEt3)2(n-Bu4N)2[Mo8O20(NNPh)6] and comparison to the structures of the parent oxomolybdate .alpha.-(n-Bu4N)4[Mo8O26] and the tetranuclear (diazenido)oxomolybdates (n-Bu4N)2[Mo4O10(OMe)2(NNPh)2] and (n-Bu4N)2[Mo4O8(OMe)2(NNC6H4NO2)4]
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