Relaxation of the H2O Overtone Bending Vibration in the Water Dimer···Hydroxyl Radical Complex

• Published in: The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 122; no. 25; pp. 5510 - 5517
• Main Author: Shin, H. K
• Format: Journal Article
• Language: English
• Published: American Chemical Society 28.06.2018

The relaxation mechanism of the overtone bending vibration in the collision of the water dimer with the vibrationally excited hydroxyl radical is studied by use of trajectory procedures. The transfer of the OH­(v = 1) energy to the dimer stretches is followed by a near-resonant first overtone transi...