Si(CO) y Negative Electrodes for Li-Ion Batteries

Si­(CO) y (0 ≤ y ≤ 0.43) alloys were synthesized by reactive gas milling silicon in CO2 at room temperature. Silicon reacts with CO2 rapidly during milling, incorporating C and O in a 1:1 ratio to form alloys consisting of Si nanograins dispersed in an amorphous Si–O–C matrix. The capacity behavior...

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Published inChemistry of materials Vol. 33; no. 18; pp. 7386 - 7395
Main Authors Cao, Yidan, Hans, Sophie, Liese, Julia, Werner-Zwanziger, Ulrike, Wang, Jun, Bennett, J. Craig, Dunlap, R. A, Obrovac, M. N
Format Journal Article
LanguageEnglish
Published American Chemical Society 28.09.2021
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Abstract Si­(CO) y (0 ≤ y ≤ 0.43) alloys were synthesized by reactive gas milling silicon in CO2 at room temperature. Silicon reacts with CO2 rapidly during milling, incorporating C and O in a 1:1 ratio to form alloys consisting of Si nanograins dispersed in an amorphous Si–O–C matrix. The capacity behavior of these alloys suggests the formation of inactive SiC and Li4SiO4 during the first lithiation. This implies that such alloys can have significantly greater initial coulombic efficiency (ICE) than SiO x at any given gravimetric or volumetric capacity.
AbstractList Si­(CO) y (0 ≤ y ≤ 0.43) alloys were synthesized by reactive gas milling silicon in CO2 at room temperature. Silicon reacts with CO2 rapidly during milling, incorporating C and O in a 1:1 ratio to form alloys consisting of Si nanograins dispersed in an amorphous Si–O–C matrix. The capacity behavior of these alloys suggests the formation of inactive SiC and Li4SiO4 during the first lithiation. This implies that such alloys can have significantly greater initial coulombic efficiency (ICE) than SiO x at any given gravimetric or volumetric capacity.
Author Cao, Yidan
Dunlap, R. A
Liese, Julia
Werner-Zwanziger, Ulrike
Hans, Sophie
Obrovac, M. N
Bennett, J. Craig
Wang, Jun
AuthorAffiliation Tsinghua-Berkeley Shenzhen Institute & Institute of Materials Research, Tsinghua Shenzhen International Graduate School
Department of Chemistry
Faculty of Physics
Ludwig-Maximilians-Universität München
College of Sustainability
Tsinghua University
Clean Technologies Research Institute
Dalhousie University
Department of Physics and Atmospheric Science
Department of Physics
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Title Si(CO) y Negative Electrodes for Li-Ion Batteries
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