[Ph3PCH2Ph]2[Zn3(tp)3Cl2] and Ni3(tma)2(H2O)8:  Two Unusual Claylike Frameworks of Metal−Polycarboxylate Coordination Polymers (tp = Terephthalate, tma = Trimesate)

• Published in: Inorganic chemistry Vol. 46; no. 19; pp. 7910 - 7916
• Main Authors: Yang, Guo-Dong, Dai, Jing-Cao, Lian, Yun-Xia, Wu, Wen-Shi, Lin, Jian-Ming, Hu, Sheng-Min, Sheng, Tian-Lu, Fu, Zhi-Yong, Wu, Xin-Tao
• Format: Journal Article
• Language: English
• Published: American Chemical Society 17.09.2007

Two new compounds, [Ph3PCH2Ph]2[Zn3(tp)3Cl2] (1) and Ni3(tma)2(H2O)8 (2) (tp = terephthalate, tma = trimesate), are metal−polycarboxylate coordination polymers prepared by similar hydrothermal synthesis techniques. X-ray single-crystal structural analysis shows that both compounds crystallize in the...