Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ‑Shaped Functional Motif Achieved by Universal Mono-Site Substitution

• Published in: Chemistry of materials Vol. 32; no. 15; pp. 6780 - 6787
• Main Authors: Huang, Qian-Ming, Hu, Chun-Li, Yang, Bing-Ping, Tang, Ru-Ling, Chen, Jin, Fang, Zhi, Li, Bingxuan, Mao, Jiang-Gao
• Format: Journal Article
• Language: English
• Published: American Chemical Society 11.08.2020

The first polar alkaline-earth metal molybdenum iodate, Ba2[MoO3(OH)­(IO3)2]­IO3, with a Λ-shaped [MoO3(OH)­(IO3)2]3– functional motif, was rationally designed. A zero-dimensional (0D) [MoO3(OH)­(IO3)2]3– unit is derived from 0D [MoO2(OH)­(IO3)3]2– polyanion through anionic mono-site substitution. B...