ansa-Zirconocene Catalysts for Isotactic-Selective Propene Polymerization at High Temperature: A Long Story Finds a Happy Ending
Kulyabin, Pavel S, Goryunov, Georgy P, Sharikov, Mikhail I, Izmer, Vyatcheslav V, Vittoria, Antonio, Budzelaar, Peter H. M, Busico, Vincenzo, Voskoboynikov, Alexander Z, Ehm, Christian, Cipullo, Roberta, Uborsky, Dmitry V
Published in Journal of the American Chemical Society (26.05.2021)
Published in Journal of the American Chemical Society (26.05.2021)
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Journal Article
A Systematic Study of the Temperature-Induced Performance Decline of ansa-Metallocenes for iPP
Ehm, Christian, Vittoria, Antonio, Goryunov, Georgy P, Izmer, Vyatcheslav V, Kononovich, Dmitry S, Kulyabin, Pavel S, Di Girolamo, Rocco, Budzelaar, Peter H. M, Voskoboynikov, Alexander Z, Busico, Vincenzo, Uborsky, Dmitry V, Cipullo, Roberta
Published in Macromolecules (10.11.2020)
Published in Macromolecules (10.11.2020)
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Journal Article
A High‐Throughput Approach to Repurposing Olefin Polymerization Catalysts for Polymer Upcycling
Cannavacciuolo, Felicia D., Yadav, Rinku, Esper, Alec, Vittoria, Antonio, Antinucci, Giuseppe, Zaccaria, Francesco, Cipullo, Roberta, Budzelaar, Peter H. M., Busico, Vincenzo, Goryunov, Georgy P., Uborsky, Dmitry V., Voskoboynikov, Alexander Z., Searles, Keith, Ehm, Christian, Veige, Adam S.
Published in Angewandte Chemie International Edition (07.06.2022)
Published in Angewandte Chemie International Edition (07.06.2022)
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Journal Article
An Integrated High Throughput Experimentation/Predictive QSAR Modeling Approach to ansa -Zirconocene Catalysts for Isotactic Polypropylene
Ehm, Christian, Vittoria, Antonio, Goryunov, Georgy P, Izmer, Vyatcheslav V, Kononovich, Dmitry S, Samsonov, Oleg V, Di Girolamo, Rocco, Budzelaar, Peter H M, Voskoboynikov, Alexander Z, Busico, Vincenzo, Uborsky, Dmitry V, Cipullo, Roberta
Published in Polymers (27.04.2020)
Published in Polymers (27.04.2020)
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Journal Article
Connection of Stereoselectivity, Regioselectivity, and Molecular Weight Capability in rac-R′2Si(2-Me-4-R-indenyl)2ZrCl2 Type Catalysts
Ehm, Christian, Vittoria, Antonio, Goryunov, Georgy P, Kulyabin, Pavel S, Budzelaar, Peter H. M, Voskoboynikov, Alexander Z, Busico, Vincenzo, Uborsky, Dmitry V, Cipullo, Roberta
Published in Macromolecules (23.10.2018)
Published in Macromolecules (23.10.2018)
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Journal Article
Rigid Postmetallocene Catalysts for Propylene Polymerization: Ligand Design Prevents the Temperature-Dependent Loss of Stereo- and Regioselectivities
Goryunov, Georgy P, Sharikov, Mikhail I, Iashin, Andrei N, Canich, Jo Ann M, Mattler, Sarah J, Hagadorn, John R, Uborsky, Dmitry V, Voskoboynikov, Alexander Z
Published in ACS catalysis (02.07.2021)
Published in ACS catalysis (02.07.2021)
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Journal Article
Reactivity of C-1-Symmetric Heteroarylamido Hafnium Complexes towards Unsaturated Electrophilic Molecules: Development of New Families of Olefin Polymerization Catalysts
Kulyabin, Pavel S., Goryunov, Georgy P., Mladentsev, Dmitry Y., Uborsky, Dmitry, Voskoboynikov, Alexander Z., Canich, Jo Ann M., Hagadorn, John R.
Published in Chemistry : a European journal (06.08.2019)
Published in Chemistry : a European journal (06.08.2019)
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Journal Article
Role of Solvent Coordination on the Structure and Dynamics of ansa -Zirconocenium Ion Pairs in Aromatic Hydrocarbons
Sian, Leonardo, Dall’Anese, Anna, Macchioni, Alceo, Tensi, Leonardo, Busico, Vincenzo, Cipullo, Roberta, Goryunov, Georgy P., Uborsky, Dmitry, Voskoboynikov, Alexander Z., Ehm, Christian, Rocchigiani, Luca, Zuccaccia, Cristiano
Published in Organometallics (14.03.2022)
Published in Organometallics (14.03.2022)
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Journal Article
Octahedral Zirconium Salan Catalysts for Olefin Polymerization: Substituent and Solvent Effects on Structure and Dynamics
Dall’Anese, Anna, Kulyabin, Pavel S., Uborsky, Dmitry V., Vittoria, Antonio, Ehm, Christian, Cipullo, Roberta, Budzelaar, Peter H. M., Voskoboynikov, Alexander Z., Busico, Vincenzo, Tensi, Leonardo, Macchioni, Alceo, Zuccaccia, Cristiano
Published in Inorganic chemistry (02.10.2023)
Published in Inorganic chemistry (02.10.2023)
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Journal Article
Reversible C-C bond formation in group 4 metal complexes: nitrile extrusion via β-aryl elimination
Kulyabin, Pavel S, Goryunov, Georgy P, Iashin, Andrei N, Mladentsev, Dmitry Y, Uborsky, Dmitry V, Ehm, Christian, Canich, Jo Ann M, Hagadorn, John R, Voskoboynikov, Alexander Z
Published in Chemical science (Cambridge) (27.08.2024)
Published in Chemical science (Cambridge) (27.08.2024)
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Journal Article
On the limits of tuning comonomer affinity of 'Spaleck-type'ansa-zirconocenes in ethene/1-hexene copolymerization: a high-throughput experimentation/QSAR approach
Ehm, Christian, Vittoria, Antonio, Goryunov, Georgy P, Izmer, Vyatcheslav V, Kononovich, Dmitry S, Samsonov, Oleg V, Budzelaar, Peter H M, Voskoboynikov, Alexander Z, Busico, Vincenzo, Uborsky, Dmitry V, Cipullo, Roberta
Published in Dalton transactions : an international journal of inorganic chemistry (07.08.2020)
Published in Dalton transactions : an international journal of inorganic chemistry (07.08.2020)
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Journal Article
Triptycene as a scaffold in metallocene catalyzed olefin polymerization
Kulyabin, Pavel S, Sharikov, Mikhail I, Izmer, Vyatcheslav V, Kononovich, Dmitry S, Goryunov, Georgy P, Alexeev, Nikita V, Uborsky, Dmitry V, Vittoria, Antonio, Antinucci, Giuseppe, Ehm, Christian, Budzelaar, Peter H. M, Cipullo, Roberta, Busico, Vincenzo, Voskoboynikov, Alexander Z
Published in Dalton transactions : an international journal of inorganic chemistry (04.06.2024)
Published in Dalton transactions : an international journal of inorganic chemistry (04.06.2024)
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Journal Article
Reactivity of C1‐Symmetric Heteroarylamido Hafnium Complexes towards Unsaturated Electrophilic Molecules: Development of New Families of Olefin Polymerization Catalysts
Kulyabin, Pavel S., Goryunov, Georgy P., Mladentsev, Dmitry Y., Uborsky, Dmitry V., Voskoboynikov, Alexander Z., Canich, Jo Ann M., Hagadorn, John R.
Published in Chemistry : a European journal (06.08.2019)
Published in Chemistry : a European journal (06.08.2019)
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Journal Article
Pyridylamido hafnium complexes with a silylene bridge: synthesis and olefin polymerization
Kulyabin, Pavel S, Uborsky, Dmitry V, Voskoboynikov, Alexander Z, Canich, Jo Ann M, Hagadorn, John R
Published in Dalton transactions : an international journal of inorganic chemistry (26.05.2020)
Published in Dalton transactions : an international journal of inorganic chemistry (26.05.2020)
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Journal Article
ansa-Metallocenes Bearing 4‑(N‑Azolyl)-2-methylindenyl and Related Ligands: Development of Highly Isoselective Catalysts for Propene Polymerization at Higher Temperatures
Izmer, Vyatcheslav V, Lebedev, Artem Y, Kononovich, Dmitry S, Borisov, Ilya S, Kulyabin, Pavel S, Goryunov, Georgy P, Uborsky, Dmitry V, Canich, Jo Ann M, Voskoboynikov, Alexander Z
Published in Organometallics (23.12.2019)
Published in Organometallics (23.12.2019)
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Journal Article
C 1 -Symmetric Si-bridged (2-indenyl)(1-indenyl) ansa-metallocenes as efficient ethene/1-hexene copolymerization catalysts
Uborsky, Dmitry V, Mladentsev, Dmitry Y, Guzeev, Bogdan A, Borisov, Ilya S, Vittoria, Antonio, Ehm, Christian, Cipullo, Roberta, Hendriksen, Coen, Friederichs, Nic, Busico, Vincenzo, Voskoboynikov, Alexander Z
Published in Dalton transactions : an international journal of inorganic chemistry (07.03.2020)
Published in Dalton transactions : an international journal of inorganic chemistry (07.03.2020)
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Journal Article
Multisubstituted C 2 -symmetric ansa -metallocenes bearing nitrogen heterocycles: influence of substituents on catalytic properties in propylene polymerization at higher temperatures
Kulyabin, Pavel S, Izmer, Vyatcheslav V, Goryunov, Georgy P, Sharikov, Mikhail I, Kononovich, Dmitry S, Uborsky, Dmitry V, Canich, Jo Ann M, Voskoboynikov, Alexander Z
Published in Dalton transactions : an international journal of inorganic chemistry (14.05.2021)
Published in Dalton transactions : an international journal of inorganic chemistry (14.05.2021)
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Journal Article
Nickel/α‐diimine catalysts in C (sp2)–C (sp2) homocoupling: An underestimated and versatile ligand family
Kudakina, Vera A., Asachenko, Andrey F., Valaeva, Valentina N., Lebedev, Artyom Y., Razavi, Abbaz, Mladentsev, Dmitry Y., Uborsky, Dmitry V., Voskoboynikov, Alexander Z.
Published in Applied organometallic chemistry (01.04.2024)
Published in Applied organometallic chemistry (01.04.2024)
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Journal Article
Hafnium vs. Zirconium, the Perpetual Battle for Supremacy in Catalytic Olefin Polymerization: A Simple Matter of Electrophilicity?
Vittoria, Antonio, Goryunov, Georgy P, Izmer, Vyatcheslav V, Kononovich, Dmitry S, Samsonov, Oleg V, Zaccaria, Francesco, Urciuoli, Gaia, Budzelaar, Peter H M, Busico, Vincenzo, Voskoboynikov, Alexander Z, Uborsky, Dmitry V, Ehm, Christian, Cipullo, Roberta
Published in Polymers (06.08.2021)
Published in Polymers (06.08.2021)
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Journal Article
On the limits of tuning comonomer affinity of ‘Spaleck-type’ ansa -zirconocenes in ethene/1-hexene copolymerization: a high-throughput experimentation/QSAR approach
Ehm, Christian, Vittoria, Antonio, Goryunov, Georgy P., Izmer, Vyatcheslav V., Kononovich, Dmitry S., Samsonov, Oleg V., Budzelaar, Peter H. M., Voskoboynikov, Alexander Z., Busico, Vincenzo, Uborsky, Dmitry V., Cipullo, Roberta
Published in Dalton transactions : an international journal of inorganic chemistry (07.08.2020)
Published in Dalton transactions : an international journal of inorganic chemistry (07.08.2020)
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Journal Article