Coligands Controlled Reactivities of Ruthenium(II) Precursors: Antiferromagnetically Coupled Ruthenium(III)-Phenoxyl versus Ruthenium(II)-Phenoxyl Forms
Samanta, Debasish, Saha, Pinaki, Maity, Suvendu, Mondal, Sudipto, Ghosh, Prasanta
Published in Inorganic chemistry (08.01.2024)
Published in Inorganic chemistry (08.01.2024)
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Glyoxalbis(2-methylmercaptoanil) complexes of nickel and ruthenium: radical versus non-radical statesElectronic supplementary information (ESI) available: X-ray crystallographic CIF files for gmma, 1·CH2Cl2, 2 and 3+Cl−·H2O; electron transfer series of gma; crystallographic data, redox potential data; mass spectrum of 4PF6; molecular geometry of gmma in crystals; EPR measurement parameters; variable temperature EPR spectra of 2−, 2+ and 3; optimized geometries of 12− as (a) bis(methylthio-imine)
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