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A convenient synthesis of difficult medium-sized cyclic peptides by Staudinger mediated ring-closureElectronic supplementary information (ESI) available: Detailed experimental procedures and 1H and 13C NMR spectra of all intermediates 1a-d, 3a-f, 4a-f, 5a-f, 7-11; 1H and 13C NMR spectra of cyclic dipeptides 6a-e. 1H NMR and HPLC-MS for cyclic tripeptide 12. CCDC 881662 and 881663 (Cartesian coordinates for the TSs for the cyclization of azido dipeptide thioesters and computational details). For
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