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Synthesis of anionic molybdenum and tungsten carbene complexes of the type [M(carbene)(CO)2(η-C5H5)]- (M=Mo or W) by the sodium naphthalide reduction of iodo carbene complexes

Synthesis of anionic molybdenum and tungsten carbene complexes of the type [M(carbene)(CO)2(η-C5H5)]- (M=Mo or W) by the sodium naphthalide reduction of iodo carbene complexes

by OSBORN, V. A, WINTER, M. J
Published in Journal of the Chemical Society. Chemical communications (1985)

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Cyclic carbene formation through alkyl migration to molybdenum coordinated isonitrile, synthesis and X-ray structure of cis-Mol-[C(NMe)[CH2]2CH2]-(CO)2(η-C5H5). An example of a sterically blocked cis-trans isomerisation for the [Mo(X)(L)(CO)2(η-C5H5)] system

Cyclic carbene formation through alkyl migration to molybdenum coordinated isonitrile, synthesis and X-ray structure of cis-Mol-[C(NMe)[CH2]2CH2]-(CO)2(η-C5H5). An example of a sterically blocked cis-trans isomerisation for the [Mo(X)(L)(CO)2(η-C5H5)] system

by ADAMS, H, BAILEY, N. A, OSBORN, V. A, WINTER, M. J
Published in Journal of organometallic chemistry (1985)

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Hydride to carbene migration at molybdenum. The isomerisation of Mo(H){=C[CH2]3NMe}(CO)2(η-C5H5) to Mo(CO)2{η2-CH[CH2]3NMe}(η-C5H5)

Hydride to carbene migration at molybdenum. The isomerisation of Mo(H){=C[CH2]3NMe}(CO)2(η-C5H5) to Mo(CO)2{η2-CH[CH2]3NMe}(η-C5H5)

by OSBORN, V. A, PARKER, C. A, WINTER, M. J
Published in Journal of the Chemical Society. Chemical communications (1986)

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Cyclic carbene complexes of the type cis-MI[H2](CO)2(η-C5H5) (M = Mo, n = 2 OR 3; M = W, n = 2): their syntheses and reactions of the molybdenum systems with LiEt3BH

Cyclic carbene complexes of the type cis-MI[H2](CO)2(η-C5H5) (M = Mo, n = 2 OR 3; M = W, n = 2): their syntheses and reactions of the molybdenum systems with LiEt3BH

by Osborn, Valerie A., Winter, Mark J.
Published in Polyhedron (01.01.1986)

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Syntheses and reactions of acyclic and cyclic carbene complexes cis-[MI(=CMeNHMe)(CO)2(η-C5H5)] (M= Mo or W) and cis-[MI{=C(CH2)nNMe}(CO)(η-C5H5)] (M= Mo, n= 3 or 4; M= W, n= 3) obtained through alkyl migration to methyl isocyanide co-ordinated to molybdenum or tungsten: X-ray structure of cis-[MoI{= C(CH2)3NMe}-(CO)2(η-C5H5)]

Syntheses and reactions of acyclic and cyclic carbene complexes cis-[MI(=CMeNHMe)(CO)2(η-C5H5)] (M= Mo or W) and cis-[MI{=C(CH2)nNMe}(CO)(η-C5H5)] (M= Mo, n= 3 or 4; M= W, n= 3) obtained through alkyl migration to methyl isocyanide co-ordinated to molybdenum or tungsten: X-ray structure of cis-[MoI{= C(CH2)3NMe}-(CO)2(η-C5H5)]

by ADAMS, H, BAILEY, N. A, OSBORN, V. A, WINTER, M. J
Published in Journal of the Chemical Society. Dalton transactions (1986)

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The addition of isonitriles to [{M(CO)(D22(η-C5H5)}2] (M = Mo or W). Syntheses and properties of [M2(υ-η2-CNR)(CO)4(η-C5H5)2] (M = Mo or W, R = Me or But) and [{Mo(CNR)(CO)2(η-C5H5)}2] (R = Me or But). X-ray crystal structures of [Mo2(υ-η2-CNBut)(CO)4(η-C5H5)2] and [{Mo(CNBut)(CO)2(η-C5H5)}2]

The addition of isonitriles to [{M(CO)(D22(η-C5H5)}2] (M = Mo or W). Syntheses and properties of [M2(υ-η2-CNR)(CO)4(η-C5H5)2] (M = Mo or W, R = Me or But) and [{Mo(CNR)(CO)2(η-C5H5)}2] (R = Me or But). X-ray crystal structures of [Mo2(υ-η2-CNBut)(CO)4(η-C5H5)2] and [{Mo(CNBut)(CO)2(η-C5H5)}2]

by ADAMS, H, BAILEY, N. A, BANNISTER, C, FAERS, M. A, FEDORKO, P, OSBORN, V. A, WINTER, M. J
Published in Journal of the Chemical Society. Dalton transactions (1987)

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