ORIGIN OF THE DISTINCTLY DIFFERENT GAS-PHASE CHEMISTRY OF LINEAR AND ALPHA-BRANCHED ALIPHATIC NITRILES WITH BARE IRON(I) IONS - EVIDENCE FOR OXIDATIVE ADDITION OF THE C-CN BOND TO FE+, NEW MECHANISMS FOR THE REDUCTIVE ELIMINATIONS OF ALKANES, AND A DEMONSTRATION OF CONSECUTIVE CH/CC BOND ACTIVATIONS OF DIFFERENT SITES OF FLEXIBLE MOLECULES
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Origin of the distinctly different gas-phase chemistry of linear and .alpha.-branched aliphatic nitriles with bare iron(I) ions. Evidence for oxidative addition of the carbon-cyano bond to iron(+), new mechanisms for the reductive eliminations of alkanes, and a demonstration of consecutive carbon-hydrogen/carbon-carbon bond activations of different sites of flexible molecules
Czekay, Gregor, Drewello, Thomas, Eller, Karsten, Zummack, Waltraud, Schwarz, Helmut
Published in Organometallics (01.10.1989)
Published in Organometallics (01.10.1989)
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