An investigation of the germylene addition reaction, GeH2+ C2H2: Time-resolved gas-phase kinetic studies and quantum chemical calculations of the reaction energy surface
BECERRA, Rosa, BOGANOV, Sergey E, EGOROV, Mikhail P, FAUSTOV, Valery I, KRYLOVA, Irina V, NEFEDOV, Oleg M, PROMYSLOV, Vladimir M, WALSH, Robin
Published in Physical chemistry chemical physics : PCCP (07.07.2004)
Published in Physical chemistry chemical physics : PCCP (07.07.2004)
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Journal Article
Unusual Isotope Effect in the Reaction of Chlorosilylene with Trimethylsilane-1-d. Absolute Rate Studies and Quantum Chemical and Rice–Ramsperger–Kassel–Marcus Calculations Provide Strong Evidence for the Involvement of an Intermediate Complex
Becerra, Rosa, Boganov, Sergey E, Egorov, Mikhail P, Krylova, Irina V, Promyslov, Vladimir M, Walsh, Robin
Published in Journal of the American Chemical Society (27.06.2012)
Published in Journal of the American Chemical Society (27.06.2012)
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Journal Article
Dramatic Isotope Effect in the Reaction of ClSiH with Trimethylsilane-1-d: Experimental Evidence for Intermediate Complexes in Silylene Si–H(D) Insertion Reactions
Becerra, Rosa, Boganov, Sergey E, Krylova, Irina V, Promyslov, Vladimir M, Walsh, Robin
Published in Organometallics (22.08.2011)
Published in Organometallics (22.08.2011)
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Journal Article
Matrix IR Study of Benzene Transformations in a Pulsed Glow Discharge in the Absence and the Presence of Oxygen
Boganov, Sergey E., Kudryashov, Sergey V., Ryabov, Andrey Yu, Suslov, Alexey I., Rynin, Stanislav S., Egorov, Mikhail P., Nefedov, Oleg M.
Published in Plasma chemistry and plasma processing (01.11.2014)
Published in Plasma chemistry and plasma processing (01.11.2014)
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Journal Article
A Highly Delocalized Triplet Carbene, 5-Methylhexa-1,2,4-triene-1,3-diyl: Matrix IR Identification, Structure, and Reactions
Boganov, Sergey E, Faustov, Valery I, Shavrin, Konstantin N, Gvozdev, Valentin D, Promyslov, Vladimir M, Egorov, Mikhail P, Nefedov, Oleg M
Published in Journal of the American Chemical Society (21.10.2009)
Published in Journal of the American Chemical Society (21.10.2009)
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Journal Article
Gas-Phase Kinetics of Chlorosilylene Reactions. I. ClSiH + Me3SiH: Absolute Rate Measurements and Theoretical Calculations for Prototype Si−H Insertion Reactions
Becerra, Rosa, Boganov, Sergey E, Egorov, Mikhail P, Faustov, Valery I, Krylova, Irina V, Nefedov, Oleg M, Promyslov, Vladimir M, Walsh, Robin
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14.05.2009)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14.05.2009)
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Journal Article
Direct Time-Resolved Study of the Gas-Phase Reactions of Germylene with Ethyl- and Diethylgermane: Absolute Rate Constants, Temperature Dependences, and Mechanism
Becerra, Rosa, Boganov, Sergey E, Egorov, Mikhail P, Krylova, Irina V, Nefedov, Oleg M, Walsh, Robin
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (01.03.2007)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (01.03.2007)
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Journal Article
Surprisingly Slow Reaction of Dimethylsilylene with Dimethylgermane: Time-Resolved Kinetic Studies and Related Quantum Chemical Calculations
Becerra, Rosa, Boganov, Sergey E, Egorov, Mikhail P, Faustov, Valery I, Krylova, Irina V, Nefedov, Oleg M, Promyslov, Vladimir M, Walsh, Robin
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (07.02.2008)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (07.02.2008)
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Journal Article
A comparison of the reactivity of germylene and dimethylgermylene with some methylgermanes. Direct kinetic and quantum chemical studies
Becerra, Rosa, Boganov, Sergey E, Egorov, Mikhail P, Faustov, Valery I, Krylova, Irina V, Nefedov, Oleg M, Promyslov, Vladimir M, Walsh, Robin
Published in Physical chemistry chemical physics : PCCP (21.08.2007)
Published in Physical chemistry chemical physics : PCCP (21.08.2007)
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Journal Article
Gas-Phase Kinetics of Chlorosilylene Reactions II. ClSiH + C2H4: Absolute Rate Measurements and Quantum Chemical and RRKM Calculations for the Prototype π Addition Reaction
Becerra, Rosa, Boganov, Sergey E., Egorov, Mikhail P., Krylova, Irina V., Nefedov, Oleg M., Promyslov, Vladimir M., Walsh, Robin
Published in Chemphyschem (01.02.2010)
Published in Chemphyschem (01.02.2010)
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Journal Article
First Gas-Phase Detection of Dimethylstannylene and Time-Resolved Study of Some of Its Reactions
Becerra, Rosa, Boganov, Sergey E, Egorov, Mikhail P, Faustov, Valery I, Krylova, Irina V, Nefedov, Oleg M, Walsh, Robin
Published in Journal of the American Chemical Society (26.06.2002)
Published in Journal of the American Chemical Society (26.06.2002)
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Journal Article
The insertion reaction of germylene into the Si-H bond of silane : absolute rate constants, temperature dependence, RRKM modelling, and quantum chemical (ab initio and DFT) calculations
BECERRA, Rosa, BOGANOV, Sergey E, EGOROV, Mikhail P, FAUSTOV, Valery I, NEFEDOV, Oleg M, WALSH, Robin
Published in Physical chemistry chemical physics : PCCP (01.01.2001)
Published in Physical chemistry chemical physics : PCCP (01.01.2001)
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Journal Article
Photoinduced reaction of dichlorosilylene with acetylene: Matrix isolation FTIR spectroscopic study
Boganov, Sergey E., Becerra, Rosa, Promyslov, Vladimir M., Shangin, Pavel G., Lalov, Andrey V., Egorov, Mikhail P., Walsh, Robin
Published in Journal of organometallic chemistry (15.03.2022)
Published in Journal of organometallic chemistry (15.03.2022)
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Journal Article
Interaction of SiCl2 with CO2 in Ar matrices
Boganov, Sergey E., Promyslov, Vladimir M., Shangin, Pavel G., Syroeshkin, Mikhail A., Egorov, Mikhail P.
Published in Mendeleev communications (01.03.2021)
Published in Mendeleev communications (01.03.2021)
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Journal Article
Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene
Boganov, Sergey E., Promyslov, Vladimir M., Rynin, Stanislav S., Krylova, Irina V., Egorov, Mikhail P.
Published in Mendeleev communications (01.11.2018)
Published in Mendeleev communications (01.11.2018)
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Journal Article
Carbenes, related intermediates, and small-sized cycles: contribution from Professor Nefedov’s laboratory
Tomilov, Yury V., Menchikov, Leonid G., Shapiro, Evgeny A., Gvozdev, Valentin D., Shavrin, Konstantin N., Volchkov, Nikolay V., Lipkind, Maria B., Egorov, Mikhail P., Boganov, Sergey E., Khabashesku, Valery N., Baskir, Esfir G.
Published in Mendeleev communications (01.11.2021)
Published in Mendeleev communications (01.11.2021)
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Journal Article
Gas‐Phase Kinetics of Chlorosilylene Reactions II. ClSiH + C 2 H 4 : Absolute Rate Measurements and Quantum Chemical and RRKM Calculations for the Prototype π Addition Reaction
Becerra, Rosa, Boganov, Sergey E., Egorov, Mikhail P., Krylova, Irina V., Nefedov, Oleg M., Promyslov, Vladimir M., Walsh, Robin
Published in Chemphyschem (01.02.2010)
Published in Chemphyschem (01.02.2010)
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Journal Article
Gas-Phase Kinetics of Chlorosilylene Reactions II. CISiH + C2H4: Absolute Rate Measurements and Quantum Chemical and RRKM Calculations for the Prototype π Addition Reaction
BECERRA, Rosa, BOGANOV, Sergey E, EGOROV, Mikhail P, KRYLOVA, Irina V, NEFEDOV, Oleg M, PROMYSLOV, Vladimir M, WALSH, Robin
Published in Chemphyschem (2010)
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Published in Chemphyschem (2010)
Journal Article
Gas-Phase Kinetics of Chlorosilylene Reactions. I. ClSiH + Me 3 SiH: Absolute Rate Measurements and Theoretical Calculations for Prototype Si−H Insertion Reactions
Becerra, Rosa, Boganov, Sergey E., Egorov, Mikhail P., Faustov, Valery I., Krylova, Irina V., Nefedov, Oleg M., Promyslov, Vladimir M., Walsh, Robin
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14.05.2009)
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14.05.2009)
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Journal Article
An investigation of the germylene addition reaction, GeH 2 + C 2 H 2 : Time-resolved gas-phase kinetic studies and quantum chemical calculations of the reaction energy surface
Becerra, Rosa, Boganov, Sergey E., Egorov, Mikhail P., Faustov, Valery I., Krylova, Irina V., Nefedov, Oleg M., Promyslov, Vladimir M., Walsh, Robin
Published in Physical chemistry chemical physics : PCCP (2004)
Published in Physical chemistry chemical physics : PCCP (2004)
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Journal Article